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\(n_{FeCl_2}=0,6.0,2=0,12(mol)\\ FeO+2HCl \to FeCl_2+H_2O\\ n_{FeO}=n_{FeCl_2}=0,12(mol)\\ m_{FeO}=0,12.72=8,6(g)\)
nH2=13,14:22,4=0,6 mol
PTHH: 2Al+6HCl=>2Al2Cl3+3H2
0,4<-1,2<----0,4<-----0,6
=> Al=0,4.27=10,8g
CMHCL=1,2:0,4=3M
CM Al2Cl3=0,4:0,4=1M
bài 2: nH2=0,2mol
PTHH: 2A+xH2SO4=> A2(SO4)x+xH2
0,4:x<---------------------------0,2
ta có PT: \(\frac{13}{A}=\frac{0,4}{x}\)<=> 13x=0,4A
=> A=32,5x
ta lập bảng xét
x=1=> A=32,5 loiaj
x=2=> A=65 nhận
x=3=> A=97,5 loại
=> A là kẽm (Zn)
a)
$n_{MgO} = \dfrac{8}{40} = 0,2(mol)$
$MgO + 2HCl \to MgCl_2 + H_2O$
$n_{MgCl_2} = n_{MgO} = 0,2(mol) \Rightarrow m_{MgCl_2} = 0,2.95 = 19(gam)$
b)
$n_{HCl} =2 n_{MgO} = 0,2.2 = 0,4(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,4.36,5}{4\%} = 365(gam)$
a) MgO + 2HCl→ MgCl2+ H2O
(mol) 0,2 0,4 0,2
\(n_{MgO}=\dfrac{m}{M}=\dfrac{8}{40}=0,2\left(mol\right)\)
→\(m_{MgCl_2}=n.M=0,2.95=19\left(g\right)\)
b) Ta có:
\(4\%=\dfrac{m_{HCl_{ }}}{m_{ddHCl}}.100\%< =>4\%=\dfrac{0,4.36,5}{m_{ddHCl}}.100\%\)
=> mdd HCl=\(\dfrac{14,6.100}{4}=365\left(g\right)\)
Vạy khối lượng dung dịch HCl cần dùng cho phản ứng là: 365g
Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
Bài 6:
\(n_{Fe\left(OH\right)_3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)
PT: \(Fe\left(OH\right)_3+3HCl\rightarrow FeCl_3+3H_2O\)
_______0,2________0,6______0,2 (mol)
a, \(C\%_{HCl}=\dfrac{0,6.36,5}{200}.100\%=10,95\%\)
b, \(C\%_{FeCl_3}=\dfrac{0,2.162,5}{21,4+200}.100\%\approx14,68\%\)
Bài 7:
\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PT: \(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)
______0,1______0,1_______0,1 (mol)
a, \(m_{ZnO}=0,1.81=8,1\left(g\right)\)
b, \(C\%_{ZnSO_4}=\dfrac{0,1.161}{8,1+100}.100\%\approx14,89\%\)
\(n_{HCl}=0.1\cdot1=0.1\left(mol\right)\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(0.05...........0.1\)
\(m_{MgO}=0.05\cdot24=1.2\left(g\right)\)
\(MgO+2HCl \to MgCl_2+H_2O\\ n_{HCl}=0,1(mol)\\ n_{MgO}=0,05(mol)\\ m_{MgO}=0,05.40=2(g)\\ \to A\)
a) PTHH: \(KOH+HCl\rightarrow KCl+H_2O\)
b) Ta có: \(n_{KCl}=0,15\cdot0,5=0,075\left(mol\right)=n_{KOH}\) \(\Rightarrow m_{KOH}=0,075\cdot56=4,2\left(g\right)\)
c) PTHH: \(KCl+AgNO_3\rightarrow KNO_3+AgCl\downarrow\)
Theo PTHH: \(n_{KCl}=0,075\left(mol\right)=n_{AgNO_3\left(p.ứ\right)}=n_{KNO_3}=n_{AgCl}\)
\(\Rightarrow n_{AgNO_3\left(dư\right)}=0,075\cdot120\%-0,075=0,015\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{AgCl}=0,075\cdot143,5=10,7625\left(g\right)\\C_{M_{KNO_3}}=\dfrac{0,075}{0,5+2}=0,03\left(M\right)\\C_{M_{AgNO_3\left(dư\right)}}=\dfrac{0,015}{2,5}=0,006\left(M\right)\end{matrix}\right.\)
d) Coi như khi cô cạn không bị hao hụt muối
Ta có: \(m_{muối.khan}=m_{KNO_3}+m_{AgNO_3\left(dư\right)}=0,075\cdot101+0,015\cdot170=10,125\left(g\right)\)
PTHH: \(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{FeCl_2}=0,2\cdot0,6=0,12\left(mol\right)=n_{FeO}\) \(\Rightarrow m_{FeO}=0,12\cdot72=8,64\left(g\right)\)