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Đề bài phải là thể tích CO2 bạn nhé!
a, PT: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
Ta có: \(n_{CaCO_3}=\dfrac{4}{100}=0,04\left(mol\right)\)
\(m_{HCl}=\dfrac{14,6.25}{100}=3,65\left(g\right)\Rightarrow n_{HCl}=\dfrac{3,65}{36,5}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,1}{2}\), ta được HCl dư.
Theo PT: \(n_{CO_2}=n_{CaCO_3}=0,04\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,04.22,4=0,896\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{CaCO_3}=0,08\left(mol\right)\\n_{CaCl_2}=n_{CaCO_3}=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,02\left(mol\right)\Rightarrow m_{HCl\left(dư\right)}=0,02.36,5=0,73\left(g\right)\)
\(m_{CaCl_2}=0,04.111=4,44\left(g\right)\)
Bạn tham khảo nhé!
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{CaCO_3}=\dfrac{4}{100}=0,04\left(mol\right)\\n_{HCl}=\dfrac{14,6\cdot25\%}{36,5}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,1}{2}\) \(\Rightarrow\) HCl còn dư, CaCO3 p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{CO_2}=n_{CaCl_2}=0,04\left(mol\right)\\n_{HCl\left(dư\right)}=0,02\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,04\cdot22,4=0,896\left(l\right)\\m_{CaCl_2}=0,04\cdot111=4,44\left(g\right)\\m_{HCl\left(dư\right)}=0,02\cdot36,5=0,73\left(g\right)\end{matrix}\right.\)
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\(n_{Cu}=\dfrac{1,28}{64}=0,02\left(mol\right)\)
PTHH: Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
0,02--------------->0,02--->0,02
=> VSO2 = 0,02.22,4 = 0,448 (l)
mCuSO4 = 0,02.160 = 3,2 (g)
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a) 2Al + 6HCl -> 2AlCl3 + 3H2
Al2O3 + 6HCl -> 2AlCl3 + 3H2O
nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol
=>%mAl=20,93% =>%mAl2O3 = 79,07%
b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g
mddY=12,9+100-0,15.2=112,6g
mAlCl3=22,5g=>C%=19,98%
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a) $2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
b) $n_{Al} = 0,45(mol) ; n_{H_2SO_4} =\dfrac{219}{980} (mol)$
Ta thấy :
$n_{Al} : 2 > n_{H_2SO_4} : 3$ nên Al dư
Theo PTHH :
$n_{Al\ pư} = \dfrac{2}{3}n_{H_2SO_4} = \dfrac{73}{490} (mol)$
$m_{Al\ dư} = 12,15 - \dfrac{73}{490}.27 = 8,127(gam)$
c) $n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = \dfrac{73}{930}(mol)$
$m_{muối} = \dfrac{73}{930}.342 = 25,48(gam)$
d) $V_{H_2} = \dfrac{219}{980}.22,4 = 5(lít)$
Hình như đề sai
a,\(n_{Al}=\dfrac{12,15}{27}=0,45\left(mol\right)\)
\(m_{H_2SO_4}=109,5.20\%=21,9\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{21,9}{98}=0,2235\left(mol\right)\)
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Đáp án C
= 0,8 mol
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O
0,8 → = 0,72 (mol)
Vkhí = 0,72.22,4 = 16,128 (lit)
nNaOH = 2 (mol)
Cl2 + 2NaOH → NaCl + NaClO + H2O
0,72 2 → 0,72 0,72 (mol)
do NaOH dư, tính theo Cl2
Dung dịch sau phản ứng: nNaCl = nNaClO = 0,72 (mol)
nNaOH dư = 0,56 (mol)
CNaCl = CNaClO = 1,44M, CNaOH = 1,12M
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\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=8,3\\ 1,5a+b=\dfrac{5,6}{22,4}=0,25\\ a=b=0,1\\ m_{Al}=27\cdot0,1=2,7g\\ m_{Fe}=8,3-2,7=5,6g\\ a=\dfrac{3a+2b}{500}\cdot36,5=3,65\%\\ m_{ddsau}=508,3-0,25\cdot2=507,8g\\ C\%_{AlCl_3}=\dfrac{133,5a}{507,8}=2,63\%\\ C\%_{FeCl_2}=\dfrac{127b}{507,8}=2,50\%\)
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(1)
$n_{H_2} = \dfrac{11,2}{22,4} = 0,5(mol)$
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,5 1 0,5 0,5 (mol)
Sau phản ứng : $m_{dd} = 0,5.24 + 100 - 0,5.2 = 111(gam)$
$C\%_{MgCl_2} = \dfrac{0,5.95}{111}.100\% = 42,79\%$
(2)
Trích mẫu thử
Cho dung dịch $H_2SO_4$ tới dư vào mẫu thử :
- mẫu thử tạo khí không màu là $Na_2CO_3$
$Na_2CO_3 + H_2SO_4 \to Na_2SO_4 + CO_2 + H_2O$
- mẫu thử tạo kết tủa trắng là $BaCl_2$
$BaCl_2 + H_2SO_4 \to BaSO_4 + 2HCl$
- mẫu thử không hiện tượng là $NaNO_3$
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\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)