\(n_{CaCO_3}=\dfrac{50}{100}=0,5\left(mol\right)\\ a,PTHH:CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ b,n_{CO_2}=n_{CaCl_2}=n_{CaCO_3}=0,5\left(mol\right)\\ V_{CO_2\left(25^oC,1bar\right)}=0,5.24,79=12,395\left(l\right)\\ c,n_{HCl}=2.0,5=1\left(mol\right)\\ V_{ddHCl}=\dfrac{1}{0,2}=5\left(l\right)\\ d,m_{CaCl_2}=111.0,5=55,5\left(g\right)\)

\(a.n_{BaCl_2}=\dfrac{20,8}{208}=0,1mol\\ n_{AgNO_3}=\dfrac{1,7}{170}=0,1mol\\ BaCl_2+2AgNO_3\rightarrow Ba\left(NO_3\right)_2+2AgCl\\ \Rightarrow\dfrac{0,1}{1}>\dfrac{0,1}{2}\Rightarrow BaCl_2.dư\\ BaCl_2+2AgNO_3\rightarrow Ba\left(NO_3\right)_2+2AgCl\)
0,05          0,1                   0,05                0,1
\(m_{Ba\left(NO_3\right)_2}=0,05.261=13,05g\\ m_{AgCl}=0,1.143,5=14,35g\\ m_{BaCl_2.dư}=\left(0,1-0,05\right).208=10,4g\\ b.V_{dd.sau}=0,03+0,07=0,1l\\ C_{M_{Ba\left(NO_3\right)_2}}=\dfrac{0,05}{0,1}=0,5M\\ C_{M_{BaCl_2.dư}}=\dfrac{0,1-0,05}{0,1}=0,5M\)

\(n_{Na_2CO_3.10H_2O}=\dfrac{85,8}{286}=0,3mol\\ m_{Na}=0,3.46=13,8g\\ m_C=0,3.12=3,6g\\ m_O=0,3.208=62,4g\\ m_H=0,3.20=6g\)

\(n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)

Gọi CTHH của oxit kim loại là M₂O_n

PT: \(M_2O_n+2nHCl\rightarrow2MCl_n+nH_2O\)

Theo PT: \(n_{M_2O_n}=\dfrac{1}{2n}n_{HCl}=\dfrac{0,15}{n}\left(mol\right)\)

\(\Rightarrow M_{M_2O_n}=\dfrac{8}{\dfrac{0,15}{n}}=\dfrac{160}{3}n\left(g/mol\right)\)

\(\Rightarrow2M_M+16n=\dfrac{160}{3}n\)

\(\Rightarrow M_M=\dfrac{56}{3}n\left(g/mol\right)\)

Với n = 3, M_M = 56 (g/mol) là thỏa mãn.

→ M là Fe.

Vậy: CTHH cần tìm là Fe₂O₃.

Ta có: \(n_{KOH}=0,02.0,2=0,004\left(mol\right)\)

PT: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

______0,004_____0,002____0,002 (mol)

\(\Rightarrow a=m_{K_2SO_4}=0,002.174=0,348\left(g\right)\)

\(V=V_{H_2SO_4}=\dfrac{0,002}{0,5}=0,004\left(l\right)=4\left(ml\right)\)

\(C_nH_{2n-2}+\dfrac{3n-1}{2}O_2\underrightarrow{t^o}nCO_2+\left(n-1\right)H_2O\)

\(M_A=23.2=46g/mol\\ n_{CO_2}=\dfrac{8,8}{44}=0,2mol\Rightarrow n_C=n_{CO_2}=0,2mol\\ \Rightarrow n_O=2n_{CO_2}=0,4mol\\ n_{H_2O}=\dfrac{5,4}{18}=0,3mol\\ \Rightarrow n_H=2n_{H_2}=0,6mol\\ \Rightarrow n_O=n_{H_2O}=0,3mol\\ n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\\ BTKL:m_A+m_{O_2}=m_{CO_2}+m_{H_2O}\\ \Rightarrow m_A=m_{H_2O}+m_{CO_2}-m_{O_2}\\ =8,8+5,4-0,3.32=4,6g\\ Có:m_{O_2}< m_{O\left(H_2O\right)}+m_{O\left(CO_2\right)}\\ \left(0,3.32< 0,4.16+0,3.16\right)\\ \Rightarrow A.có.O\\ m_{O\left(A\right)}=4,6-0,2.12-0,6.1=1,6g\\ CTHH\left(A\right):C_xH_yO_z\)
Ta có tỉ lệ:

\(\dfrac{0,2.12}{12x}=\dfrac{0,6.1}{y}=\dfrac{1,6}{16z}=\dfrac{4,6}{46}\\ \Rightarrow\left\{{}\begin{matrix}x=2\\y=6\\z=1\end{matrix}\right.\)

Vậy CTHH A cần tìm là \(C_2H_6O\)

\(a)n_{Zn}=a;n_{Fe}=b\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ a.....2a.......a........a\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b.....2b.......b........b\\ \Rightarrow\left\{{}\begin{matrix}65a+56b=24,2\\136a+127b=52,6\end{matrix}\right.\\ \Rightarrow a=b=0,2mol\\ n_{H_2}=0,2+0,2=0,4mol\\ V=V_{H_2}=0,4.22,4=8,96l\\ n_{HCl}=0,2.2+0,2.2=0,8mol\\ 200ml=0,2l\\ C_{M_{HCl}}=\dfrac{0,8}{0,2}=4M\\ b)n_{CuO}=x;n_{Fe_2O_3}=y\\ CuO+H_2\xrightarrow[]{t^0}Cu+H_2O\\ x.....x.......x.....x\\ Fe_2O_3+3H_2\xrightarrow[]{t^0}2Fe+3H_2O\\ y.........3y......2y.....3y\)
\(\Rightarrow\left\{{}\begin{matrix}x+3y=0,4\\80x=160y\end{matrix}\right.\\ \Rightarrow x=0,16mol;y=0,08mol\\ m=m_{CuO}+m_{Fe_2O_3}=0,16.80+0,08.160=25,6g\)

\(16,8l\left(đktc\right)?\\ n_{KK}=\dfrac{16,8}{22,4}=0,75mol\\ n_{O_2}=0,75\cdot20\%:100\%=0,15mol\\ m_{O_2}=0,15.32=4,8g\\ BTKL:m_X+m_{O_2}=m_Y\\ \Rightarrow m_Y=m_X+m_{O_2}\\ \Rightarrow m_Y=m=11,2+4,8=16g\)