Giúp mình câu 1 tới câu 20 (mình cần gấp ạ)
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\(SO_3+H_2O\rightarrow H_2SO_4\\ H_2SO_4+Na_2SO_3\rightarrow Na_2SO_4+SO_2+H_2O\\ SO_2+Na_2O\rightarrow Na_2SO_3\\ Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
1, SO3+H2O->H2SO4
2, H2SO4+Na2SO3->Na2SO4+H2O+SO2
3, SO2+2NaOH->Na2SO3+H2O
4, Na2SO3+H2SO4->Na2SO4+H2O+SO2
a, \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
Ta có: \(n_{Al_2O_3}=\dfrac{15,3}{102}=0,15\left(mol\right)\)
b, \(n_{AlCl_3}=2n_{Al_2O_3}=0,3\left(mol\right)\Rightarrow m_{AlCl_3}=0,3.133,5=40,05\left(g\right)\)
c, \(n_{HCl}=6n_{Al_2O_3}=0,9\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,9.36,5}{14,6\%}=225\left(g\right)\)
d, m dd sau pư = 15,3 + 225 = 240,3 (g)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{40,05}{240,3}.100\%\approx16,67\%\)
e, nH2SO4 = 0,3.1 = 0,3 (mol)
PT: \(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,3}{3}\), ta được Al2O3 dư.
→ Al2O3 không tan hết.
A: MgO, CuO
B: MgCl2, CuCl2
C: Mg(OH)2, Cu(OH)2
PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{FeO}=\dfrac{2,16}{72}=0,03\left(mol\right)\\ n_{HCl}=0,2.0,4=0,08\left(mol\right)\\ a,PTHH:FeO+2HCl\rightarrow FeCl_2+H_2O\\ Vì:\dfrac{0,03}{1}< \dfrac{0,08}{2}\Rightarrow HCldư\\ n_{FeCl_2}=n_{FeO}=0,03\left(mol\right)\\ m_{FeCl_2}=127.0,03=3,81\left(g\right)\\ n_{HCl\left(Dư\right)}=0,08-2.0,03=0,02\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,4\left(l\right)\\ C_{MddHCl\left(dư\right)}=\dfrac{0,02}{0,4}=0,05\left(M\right);C_{MddFeCl_2}=\dfrac{0,03}{0,4}=0,075\left(M\right)\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
Oxit: MO.
Gọi: nCuO = a (mol) → nMO = 2a (mol)
⇒ 80a + (MM + 16).2a = 3,6 (1)
Có: nHNO3 = 0,06.2,5 = 0,15 (mol)
BTNT Cu: nCu(NO3)2 = nCu = a (mol)
BTNT M: nM(NO3)2 = nM = 2a (mol)
BT e, có: 2nCu = 3nNO \(\Rightarrow n_{NO}=\dfrac{2}{3}n_{Cu}=\dfrac{2}{3}a\left(mol\right)\)
BTNT N, có: \(2n_{Cu\left(NO_3\right)_2}+2n_{M\left(NO_3\right)_2}+n_{NO}=n_{HNO_3}\)
\(\Rightarrow2a+2.2a+\dfrac{2}{3}a=0,15\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,0225\left(mol\right)\\M_M=24\left(g/mol\right)\end{matrix}\right.\)
→ M là Mg.
Đáp án: B