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Sửa đề H2SO2 thành H2SO4
\(n_{Ba^{2+}}=n_{Ba\left(OH\right)2}=0,01.0,1=0,001\left(mol\right)\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)2}=2.0,001=0,002\left(mol\right)\)
\(n_{SO_4^{2-}}=n_{H2SO4}=0,1.0,05=0,005\left(mol\right)\)
\(\Rightarrow n_{H^+}=2n_{H2SO4}=2.0,005=0,01\left(mol\right)\)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
0,001 0,01 0,01
Xét tỉ lệ : \(0,001< 0,01\Rightarrow SO_4^{2-}dư\)
\(n_{Ba^{2+}\left(pư\right)}=n_{BaSO4}=0,001\left(mol\right)\Rightarrow m_{BaSO4}=0,001.233=0,233\left(g\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,01 0,002
Xét tỉ lệ : \(0,01>0,002\Rightarrow H^+dư\)
\(n_{H^+dư}=0,01-0,002=0,008\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,008}{0,1+0,1}=0,04M\)
\(\Rightarrow pH=-log\left(0,04\right)\approx1,4\)
\(nH^+\)= nHCl=0,0002(mol)
\(nOH^-\)=2.0,02.0,03=0,0012(mol)
\(H^+\) + \(OH^-\)\(\rightarrow\)H2O
0,0002(mol) \(\rightarrow\) 0,0002(mol)
=> n\(OH^-\)dư = 0,001(mol)
=> CM OH- =\(\dfrac{0,001}{0,5}\)=\(2.10^{-3}\)(CM)
=> CM H+=\(5.10^{-12}\)
=> ph= -lg(\(5.10^{-12}\))=11,3
Bài 1:
Ta có: \(\Sigma n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,05.0,01+0,05.0,005.2=0,001\left(mol\right)\)
\(n_{H^+}=n_{HCl}=0,05.0,015=0,00075\left(mol\right)\)
PT ion: \(OH^-+H^+\rightarrow H_2O\)
______0,001__0,00075 (mol)
⇒ OH- dư. nOH- (dư) = 2,5.10-4 (mol)
\(\Rightarrow\left[OH^-\right]=\frac{2,5.10^{-4}}{0,1}=2,5.10^{-3}M\Rightarrow\left[H^+\right]=4.10^{-12}M\)
\(\Rightarrow pH\approx11,4\)
Bài 2: Đáp án D
Giải:
Ta có: \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1.0,002+0,2.2.x=2.10^{-4}+0,4x\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\frac{2.10^{-4}+0,4x}{0,3}M\)
\(\Rightarrow pH=-log\left(\frac{2.10^{-4}+0,4x}{0,3}\right)=2,7\)
\(\Rightarrow x\approx9,964.10^{-4}\approx10^{-3}\)
Bạn tham khảo nhé!
\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)
\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
Lập tỉ lệ :
\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)
\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)
\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)
\(pH=-log\left(0.01\right)=2\)
\(b.\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.001..........0.002\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)
PT ion: \(H^++OH^-\rightarrow H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{H^+}=0,15\cdot0,05=0,0075\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\) H+ còn dư 0,0065 mol
\(\Rightarrow\left[H^+\right]=\dfrac{0,0065}{0,2}=0,0325\left(M\right)\) \(\Rightarrow pH=-log\left(0,0325\right)\approx1,5\)