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Câu 1 :
PTHH :
\(2KMnO_4+3H_2SO_4+10HCl\rightarrow5Cl_2+8H_2O+2MnSO_4+K_2SO_4\)
\(Cl_2+2KOH\rightarrow H_2O+KCl+KClO\)
\(KClO+2HCl\rightarrow KCl+H_2O+Cl_2\)
\(2KCl+2H_2O\rightarrow2KOH+Cl_2+H_2\)
\(C_2H_4Br_2+2KOH\rightarrow C_2H_2+2H_2O+2KBr\)
\(2KBr+Cl_2\rightarrow2KCl+Br_2\)
\(Br_2+2KI\rightarrow I_2+2KBr\)
\(I_2+2K\rightarrow2KI\)
PTHH :
2KMnO4+3H2SO4+10HCl→5Cl2+8H2O+2MnSO4+K2SO4
Cl2+2KOH→H2O+KCl+KClO
KClO+2HCl→KCl+H2O+Cl2
2KCl+2H2O→2KOH+Cl2+H2
C2H4Br2+2KOH→C2H2+2H2O+2KBr
2KBr+Cl2→2KCl+Br2
Br2+2KI→I2+2KBr
I2+2K→2KI
2)
Cl2+2Na--->2NaCl
2NaCl+2H2O- điện phân dd->2NaOH+H2+Cl2
Cl2+Ca(OH)2 --30oC-->CaOCl2 +H2O
| 2CaOCl2 | → | O2 | + | 2CaCl2 |
CaCl2 +2AgNO3-->2AgCl+Ca(NO3)2
| 2AgCl | → | 2Ag | + | Cl2 |
Cl2+2NaOh-->NaCl+NaClO+H2O
a) 4HCl + MnO2 --> MnCl2 + Cl2 +2H2O
2Fe + 3Cl2 ---> 2FeCl3
FeCl3 + 3NaOH --> Fe(OH)3 + 3NaCl
NaCl + H2SO4 đ---> NaHSO4 + HCl
2HCl + CuO ---> CuCl2 + H2O
CuCl2 +2AgNO3 ---> Cu(NO3)2 + 2AgCl
b) 2KMnO4 + 16HCl ---> 2KCl + 2MnCL2 +5Cl2 +8H2O
Cl2 + H2--->2HCl
6HCl + Fe2O3 ---> 2FeCl3 +3H2O
FeCl3 + 3AgNO3 --> Fe(NO3)3 +3AgCl
2AgCl --to---> 2Ag + Cl2
Cl2 + 2NaBr ---> 2NaCl + Br2
Br2 + 2NaI --> 2NaBr + I2
I2 +Zn --to--> ZnI2
ZnI2 + 2NaOH --> Zn(OH)2 +2NaI
c) 2KCl ---dpnc--> 2K + Cl2
Cl2 + 2KOH --> KCl + KClO + H2O
4KClO --> KClO3 +3 KCl
4KClO3 ---> 3KClO4 + KCl
3KClO4 + 8Al ---> 4Al2O3 + 3KCl
KCl + AgNO3 --> AgCl + KNO3
d) 3Cl2 + 6KOH ---> KClO3 + 5KCl +3H2O
2KClO3 ---> 2KCl +#O2
2KCl --> 2K + Cl2
2Cl2 + Ca(OH)2 ---> CaCl2 +Ca(ClO)2
Ca(ClO)2 ---> CaCl2 + O2
CaCl2 ---> Ca + Cl2
Cl2 ra O2 ????
e)6HCl + KClO3 ---> KCl +3Cl2 +3H2O
3Cl2 +6KOH --> 5KCl + KClO +3 H2O
2KClO3 --> 2KCl + 3O2
2KCl --> 2K + CL2
CL2 +H2 --> 2HCl
2HCl +Fe--> FeCl2 + H2
Cl2 + 2FeCl2 -->2FeCl3
FeCl3 +3NaOH --> Fe(OH)3 +3NaCl
a) (1) MnO2 + 4 HCl(đặc) -to-> MnCl2 + Cl2 + 2 H2O
(2) Cl2 + H2 \(\Leftrightarrow\) 2 HCl
(3) HCl + NaOH -> NaCl + H2O
(4) 2 NaCl + 2 H2O -đpddcmnx-> 2 NaOH + H2 + Cl2
(5) Cl2 + 2 H2O + SO2 -> H2SO4 + 2 HCl
(6) H2SO4 + BaCl2 -> BaSO4 + 2 HCl
b)
(1) BaCl2 -điện phân nóng chảy nhiệt độ cao-> Ba + Cl2
(2) Cl2 + H2 \(\Leftrightarrow\) 2 HCl
(3) Fe + 2 HCl -> FeCl2 + H2
(4) 2 FeCl2 + Cl2 -to-> 2 FeCl3
(5) 2 FeCl3 + 3 Ba(OH)2 -> 2 Fe(OH)3 +3 BaCl2
(6) BaCl2 + H2SO4 -> BaSO4 + 2 HCl
c) (1) BaCl2 + H2SO4 -> BaSO4 +2 HCl
(2) 2 HCl + CuO -> CuCl2 + H2O
(3) CuCl2 + 2 KOH -> Cu(OH)2 + 2 KCl
(4) KCl + H2O -đpddcmnx-> KOH + 1/2 Cl2 + 1/2 H2
(5) 6 KOH + 3 Cl2 -to->5 KCl + KClO3 +3 H2O
(6) 2 KClO3 -to-> 2 KCl + 3 O2
a)
(1) MnO2 + 4HCl(đ) -to-> MnCl2 + Cl2 + 2H2O
(2) Cl2 + H2 <-as-> 2 HCl
(3) HCl + NaOH => NaCl + H2O
(4) 2NaCl + 2H2O -đpddcmn-> 2NaOH + H2 + Cl2
(5) Cl2 + 2H2O + SO2 => H2SO4 + 2HCl
(6) H2SO4 + BaCl2 => BaSO4 + 2HCl
b)
(1) BaCl2 -đpdd-> Ba + Cl2
(2) Cl2 + H2 ⇔ 2HCl (Đk : ánh sáng hoặc nhiệt độ)
(3) Fe + 2HCl => FeCl2 + H2
(4) 2FeCl2 + Cl2 -to-> 2FeCl3
(5) 2FeCl3 + 4Ba(OH)2 => 2Fe(OH)3 + 3BaCl2
(6) BaCl2 + H2SO4 => BaSO4 + 2HCl
c)
(1) BaCl2 + H2SO4 => BaSO4 +2HCl
(2) 2HCl + CuO => CuCl2 + H2O
(3) CuCl2 + 2KOH => Cu(OH)2 + 2KCl
(4) 2KCl + 2H2O -đpddcmn-> 2KOH + Cl2 + H2
(5) 6KOH + 3Cl2 -to-> 5KCl + KClO3 +3H2O
(6) 2KClO3 -to-> 2KCl + 3O2
3 ý cuối:
2KNO3 + 3C + S \(\rightarrow\)K2S + 3CO2 + N2
(5x-2y)Al +(18x-6y) HNO3 \(\rightarrow\) (5x-2y)Al(NO3)3 +3 NxOy + (9x-3y)H2O
2FexOy + (6x-2y)H2SO4\(\rightarrow\)xFe2(SO4)3 + (3x-2y)SO2 +(6x-2y) H2O
\(3I_2+6KOH\rightarrow KIO_3+3H_2O+5KI\)
\(Br_2+2KI\rightarrow I_2+2KBr\)
\(Cl_2+2KBr\rightarrow Br_2+2KCl\)
\(Br_2+2Na\rightarrow2NaBr\)
\(Cl_2+2NaBr\rightarrow Br_2+2NaCl\)
\(2H_2O+2NaCl\rightarrow Cl_2+H_2+2NaOH\)
\(3Cl_2+6KOH\rightarrow3H_2O+5KCl+KClO_3\)
\(2KClO_3\rightarrow2KCl+3O_2\)
\(2H_2O+2KCl\rightarrow Cl_2+H_2+2KOH\)
\(2KMnO_4+16HCl\rightarrow2KCl+2MnCl_2+5Cl_2+8H_2O\)
\(2Na+Cl_2\rightarrow2NaCl\)
\(2NaCl+H_2SO_4\rightarrow Na_2SO_4+2HCl\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2AgNO_3\rightarrow2AgCl+Mg\left(NO_3\right)_2\)
\(2AgCl\rightarrow2Ag+Cl_2\)
a, \(C_2H_2+Cl_2\rightarrow C+2HCl\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\)
\(2KCl+2H_2O\rightarrow2KOH+Cl_2+H_2\) ( đpcmn )
\(6KOH+3Cl_2\rightarrow KClO_3+5KCl+3H_2O\)
\(KClO_3+6HCl\rightarrow KCl+3Cl_2+3H_2O\)
b, \(NaCl+H_2SO_4\rightarrow NaHSO_4+HCl\) ( NaCl khan , H2SO4 đặc nóng )
\(2HCl\rightarrow H_2+Cl_2\) ( Đpdd )
\(6KOH+3Cl_2\rightarrow KClO_3+5KCl+3H_2O\)
\(KClO_3+6HCl\rightarrow KCl+3Cl_2+3H_2O\)
\(2KCl\rightarrow2K+Cl_2\) ( Đpdd )
\(Cl_2+Ca\left(OH\right)_2\rightarrow CaOCl_2+H_2O\)
KCl ra Cl2 không dùng dùng đpdd mà dùng điện phân nóng chảy nhé