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Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
BTNT, có: \(n_{SO_4}=n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\)
Mà: m muối = mKL + mSO4
⇒ m = mKL = 93,6 - 0,6.96 = 36 (g)
Bạn tham khảo nhé!
MnO2+4HCl->MnCl2+H2O+Cl2
0,5---------2------0,5--------0,5---0,5
Cl2+2NaOH->NaClO+NaCl+H2O
0,5-----1--------0,5----------0,5------0,5
n MnO2 =\(\dfrac{43.5}{87}\)=0,5 mol
n NaOH=5.0,4=2 mol
=>NaOH dư :0,1 mol
=>CM NaCl= CM NaClO =\(\dfrac{1}{0,4}\)=2,5M
=>CM NaOH dư =1\(\dfrac{1}{0,4}\)=2,5M
b)
C%HCl =\(\dfrac{2.36,5}{250}100\)=29,2%
dùng dư 10%
=>C%HCl=29,2+10=39,2%
Dùng dư 10% ở đây là
số mol HCl cần: 2 mol
→ số mol HCl dư: 2*10% = 0,2 mol
→ tổng số mol HCl đã sử dụng là 2,2 mol
→ C%HCl = (2,2*36,5)/250 . 100 = 32,12%
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}=0,5\left(mol\right)\\n_{H_2}=n_{Fe}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)
\(a=C_{M_{HCl}}=\dfrac{0,5}{0,1}=5\left(M\right)\)
b, Theo PT: \(n_{FeCl_2}=n_{Fe}=0,25\left(mol\right)\)
Ta có: \(n_{AgNO_3}=0,4.1,3=0,52\left(mol\right)\)
PT: \(2AgNO_3+FeCl_2\rightarrow Fe\left(NO_3\right)_2+2AgCl_{\downarrow}\)
______0,5______0,25______0,25________0,5 (mol)
\(AgNO_3+Fe\left(NO_3\right)_2\rightarrow Fe\left(NO_3\right)_3+Ag_{\downarrow}\)
0,02______0,02________0,02________0,02 (mol)
⇒ m = mAgCl + mAg = 0,5.143,5 + 0,02.108 = 73,91 (g)
- Dd sau pư gồm: Fe(NO3)3: 0,02 (mol) và Fe(NO3)2: 0,25 - 0,02 = 0,23 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe\left(NO_3\right)_3}}=\dfrac{0,02}{0,1+0,4}=0,04\left(M\right)\\C_{M_{Fe\left(NO_3\right)_2}}=\dfrac{0,23}{0,1+0,4}=0,46\left(M\right)\end{matrix}\right.\)
\(Fe+2HCl->FeCl_2+H_2\\ a.V=\dfrac{14}{56}\cdot22,4=5,6\left(L\right)\\ a=\dfrac{\dfrac{14}{56}\cdot2}{0,1}=5\left(M\right)\\ b.n_{AgNO_3}=0,4\cdot1,3=0,52mol\\ FeCl_2+AgNO_3->Fe\left(NO_3\right)_2+AgCl\\ Fe\left(NO_3\right)_2+AgNO_3->Ag+Fe\left(NO_3\right)_3\\ m=0,25\cdot143,5+0,25\cdot108=62,875\left(g\right)\\ C_{M\left(AgNO_3\right)}=\dfrac{0,02}{0,5}=0,04M\\ C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,25}{0,5}=0,5M\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
a) Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow n_{H_2SO_4}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3\cdot98}{10\%}=294\left(g\right)\)
b) Theo PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2}=0,3\cdot2=0,6\left(g\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=298,8\left(g\right)\)
\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{298,8}\cdot100\%\approx11,45\%\)