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Đầu tiên phải đổi về số mol đã:
nO2=10,0822,4=0,45(mol)nO2=10,0822,4=0,45(mol)
PTHH: 2 KMnO4
K2MnO4 + MnO2 + O2
pt 2 1 1 1
Mol 0,9 0,45 0,45 0,45
Hp/ứ = 80% m KMnO4 ban đầu = 0,9.158.10080=177,75(gam)0,9.158.10080=177,75(gam)
nKMnO4 ban đầu = 177,75: 158 = 1,125 mol
nKMnO4 dư= 1,125 – 0,9 = 0,225 mol.
Thuốc tím có lẫn 10% tạp chất
m thuốc tím = 177,75.10090=197,5(gam)177,75.10090=197,5(gam)
Khối lượng chất rắn sau phản ứng: 197,5 – 0,45.32 = 183,1 gam
Chất rắn sau phản ứng gồm KMnO4 dư, K2MnO4, MnO2, tạp chất.
%MnO2/CR= 0,45.87183,1.100%=21,38(%)0,45.87183,1.100%=21,38(%)
%K2MnO4/CR= 0,45.197183,1.100%=48
\(n_K=n_{O_2}=\dfrac{V}{22,4}=0,45\left(mol\right)\)
\(PTHH:2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
....................0,9..............................................0,45........
\(\Rightarrow m_{KMnO_4}=n.M=142,2\left(g\right)\)
Mà H = 80 %
\(\Rightarrow m_{KMnO_4tg}=177,75\%\)
Lại có : Trong m g thuốc tím chỉ có 90% phản ứng .
\(\Rightarrow m=197,5\left(g\right)\)
Vậy ...
1) Gọi số mol P2O5 là a (mol)
PTHH: P2O5 + 3H2O --> 2H3PO4
a----------------->2a
\(m_{H_3PO_4\left(tổng\right)}=98.2a+\dfrac{10.200}{100}=196a+20\left(g\right)\)
mdd sau pư = 142a + 200 (g)
=> \(C\%_{dd.sau.pư}=\dfrac{196a+20}{142a+200}.100\%=17,93\%\)
=> a = 0,093 (mol)
=> mP2O5 = 0,093.142 = 13,206 (g)
2)
a) \(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,9<-----------0,45<----0,45<----0,45
=> \(m_{KMnO_4\left(Pư\right)}=0,9.158=142,2\left(g\right)\)
=> \(m_{KMnO_4\left(tt\right)}=\dfrac{142,2.100}{80}=177,75\left(g\right)\)
=> \(m=\dfrac{177,75.100}{90}=197,5\left(g\right)\)
b)
X \(\left\{{}\begin{matrix}m_{K_2MnO_4}=0,45.197=88,65\left(g\right)\\m_{MnO_2}=0,45.87=39,15\left(g\right)\\m_{KMnO_4}=177,75-142,2=35,55\left(g\right)\\m_{tạp.chất}=197,5.10\%=19,75\left(g\right)\end{matrix}\right.\)
\(a)n_{KMnO_4} = a; n_{KClO_3} = b\Rightarrow 158a + 122,5b = 99,95(1)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{O_2} = 0,5a +1,5b = \dfrac{14,56}{22,4}=0,65(2)\\ (1)(2)\Rightarrow a = 0,4 ; b = 0,3\\ \%m_{KMnO_4} = \dfrac{0,4.158}{99,95}.100\% = 63,23\%\\ \%m_{KClO_3} = 100\%-63,23\% = 36,77\%\)
\(n_{K_2MnO_4} = n_{MnO_2} = 0,5a = 0,2(mol)\\ n_{KClO_3} = b = 0,3(mol)\\ m_{hh\ sau\ pư} = 99,95 - 0,65.32 = 79,15(gam)\\ \%m_{K_2MnO_4} = \dfrac{0,2.197}{79,15}.100\% = 49,78\%\\ \%m_{MnO_2} = \dfrac{0,2.87}{79,15},100\% = 21,98\%\\ \%m_{KCl} = 28,24\%\)
ko khó lém bn ơi có câu nèo easy hơm ko
a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\) (1)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\) (2)
Theo PT (1): \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Al_2O_3}=15,6-5,4=10,2\left(g\right)\end{matrix}\right.\)
b) \(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
Theo PT (1), (2): \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}+n_{Al_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{mu\text{ố}i}=m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)
c) Theo PT (1), (2): \(n_{H_2SO_4}=n_{H_2}+3n_{Al_2O_3}=0,6\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(c\text{ần}.d\text{ùng}\right)}=0,6.98=58,8\left(g\right)\)
\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
\(a)2Cu+O_2\xrightarrow[]{t^0}2CuO\)
\(b)n_{CuO}=a;n_{Cu\left(dư\right)}=b\\ 80.20\%a-64b=0\left(1\right)\\ n_{Cu\left(PƯ\right)}=n_{CuO}=a\\ 64a+64b=33,6\left(2\right)\\ \left(1\right)\&\left(2\right)\Rightarrow a=0,42;b=0,105\\ m_{Cu\left(pư\right)}=0,42.64=26,88g\\ n_{O_2}=\dfrac{1}{2}\cdot0,42=0,21mol\\ m_{O_2}=0,21.32=6,72g\\ c)m_{kk}=6,72:20\%=33,6g\)
nO2=10,08/22,4=0,45(mol)
2KMnO4--t*->K2MnO4+MnO2+O2
0,9____________0,45_____0,45__0,45
mKMnO4=0,9.158=142,2(g)
=>m tạp chất=142,2.10/90=15,8(g)
mK2MnO4=0,45.197=88,65(g)
mMnO2=0,45.87=39,15(g)
=>mX=39,15+88,65+15,8=143,6(g)
=>%m tạp chất=15,8/143,6.100%=11%
%mK2MnO4=88,65/143,6.100%=61,7%
=>%mMnO2=100%-61,7%-11%=27,3%