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a) H2SO4 + 2NaOH --> Na2SO4 + 2H2O
b) \(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
PTHH: H2SO4 + 2NaOH --> Na2SO4 + 2H2O
0,2---->0,4
=> mNaOH = 0,4.40 = 16 (g)
=> \(m_{dd.NaOH}=\dfrac{16.100}{20}=80\left(g\right)\)
c)
PTHH: H2SO4 + 2KOH --> K2SO4 + 2H2O
0,2---->0,4
=> mKOH = 0,4.56 = 22,4 (g)
=> \(m_{dd.KOH}=\dfrac{22,4.100}{5,6}=400\left(g\right)\)
=> \(V_{dd.KOH}=\dfrac{400}{1,045}=382,775\left(ml\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ pthh:H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2 0,4
\(m_{\text{ }NaOH}=0,4.40=16g\\ m_{\text{dd}NaOH}=\dfrac{16.100}{20}=80g\)
\(pthh:H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,2 0,4
\(m_{KOH}=0,4.56=22,4g\\
m_{\text{dd}KOH}=\dfrac{22,4.100}{5,6}=400g\\
V_{\text{dd}}=\dfrac{400}{1,045}=382,7ml\)
\(V_{dd}=\dfrac{22,4}{1,045}=21,4354ml\)
Theo đề bài: \(n_{HCl}=\frac{200}{1000}.1=0,2\left(mol\right)\)
PTHH: \(NaOH+HCl\rightarrow NaCl+H_2\uparrow\)
\(0,2\left(mol\right)\) \(0,2\left(mol\right)\)
\(\Rightarrow\) \(m_{NaOH}=0,2.40=8\left(g\right)\)
Vậy để trung hòa hết 200ml dd HCl 1M thì cần 8 gam NaOH
200ml = 0,2 l
số mol NAOH có trong dd là:
adct CM = n / V suy ra : n= Cm . V
n= 0,2 . 1= 0.2 mol
mNAOH= 0,2 . 40=8 (g)
Ta có:
\(V_{Dd_{NaOH}}=\frac{200}{1000}=0,2\left(l\right)\)
\(V_{dd_{HCl}}=\frac{300}{1000}=0,3\left(l\right)\)
\(V_{dd_{Ba\left(OH\right)2}}=\frac{25}{1000}=0,025\left(l\right)\)
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\)
\(n_{Ba\left(OH\right)2}=0,025.0,5=0,0125\left(mol\right)\)
\(n_{HCl}=0,3.1=0,3\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(n_{HCl_{pư}}=0,2\left(mol\right)\)
Vì n NaOH < n HCl
\(\Rightarrow n_{HCl_{dư}}=n_{HCl_{bđ}}-n_{HCl_{pư}}=0,3-0,2=0,1\left(mol\right)\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(M_2CO_3+2HCl\rightarrow2MCl+H_2O+CO_2\)
a---------->2a--------------------------->a
\(MHCO_3+HCl\rightarrow MCl+H_2O+CO_2\)
b---------->b---------------------------->b
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,1----->0,1
\(\left\{{}\begin{matrix}a+b=n_{CO_2}=0,3\\2a+b+0,1=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\)
=> \(0,1\left(2M+60\right)+0,2\left(M+61\right)=27,4\Rightarrow M=23\)
M là Na
Hai muối ban đầu là \(Na_2CO_3,NaHCO_3\)
\(m_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)
\(m_{NaHCO_3}=0,2.84=16,8\left(g\right)\)
b. Trong đề không có đề cập tới V bạn.
1.
Al2O3 + 2NaOH -> 2NaAlO2 + H2O (1)
nNaAlO2=0,225(mol)
Từ 1:
nNaOH=nNaAlO2=0,225(mol)
nal2O3=\(\dfrac{1}{2}\)nNaAlO2=0,1125(mol)
V dd NaOH=0,225:5=0,045(lít)
mAl2O3=0,1125.102=11,475(g)
mquặng=11,475.110%=12,6225(g)
a) $2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
b)
n H2SO4 = 0,03.1 = 0,03(mol)
n NaOH = 2n H2SO4 = 0,06(mol)
=> CM NaOH = 0,06/0,05 = 1,2M
c) $H_2SO_4 + 2KOH \to K_2SO_4 + 2H_2O$
n KOH = 2n H2SO4 = 0,06(mol)
=> m KOH = 0,06.56 = 3,36 gam
=> m dd KOH = 3,36/5,6% = 60(gam)
=> V dd KOH = m/D = 60/1,045 = 57,42(ml)
Ta có; \(\left\{{}\begin{matrix}n_{NaOH}=0,02.2=0,04\left(mol\right)\\n_{KOH}=0,01.2=0,02\left(mol\right)\end{matrix}\right.\)
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
pư..............0,04..........0,02..............0,02............0,04 (mol)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
pư............0,02..........0,01.............0,01...........0,02 (mol)
\(\Rightarrow C_{M_{ddH2SO4}}=\dfrac{0,02+0,01}{0,03}=1\left(M\right)\)
Tương tự ta có:\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,02.1=0,02\left(mol\right)\\n_{HCl}=0,005.1=0,005\left(mol\right)\end{matrix}\right.\)
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
pư.............0,04.............0,02............0,02............0,04 (mol)
PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
pư............0,005.....0,005.......0,005.....0,005 (mol)
\(\Rightarrow C_{M_{ddNaOH}}=\dfrac{0,04+0,005}{0,03}=3\left(M\right)\)
Vậy......
Bài 13 :
\(a)n_{Fe_2O_3} = \dfrac{9,6}{160} = 0,06(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{HCl} = 6n_{Fe_2O_3} = 0,36(mol)\\ C\%_{HCl} = \dfrac{0,36.36,5}{150}.100\% = 8,76\%\\ \Rightarrow X = 8,76 b) n_{FeCl_3} = 2n_{Fe_2O_3} = 0,12(mol)\\ m_{FeCl_3} = 0,12.162,5 =19,5(gam)\)
\(n_{HCl}=0,2.1=0,2\left(mol\right)\)
PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
________0,2<-------0,2__________________(mol)
=> \(m_{NaOH}=40.0,2=8\left(g\right)\)
=> mdd NaOH 10% = \(\frac{8.100}{10}=80\left(g\right)\)
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