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a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\Rightarrow m_{FeSO_4}=0,1.152=15,2\left(g\right)\)
b, \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, Sửa đề: 500 ml → 500 (g)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,1\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,1.98}{500}.100\%=1,96\%\)
nH2=0,15 mol
2Al+3H2SO4=>Al2(SO4)3+3H2
0,1 mol<= 0,15 mol
mAl=0,1.27=2,7g
nAl2(SO4)3=0,05 mol
=>mAl2(SO4)3=342.0,05=17,1g
nH2SO4=0,15 mol=>mH2SO4=14,7
mdd H2SO4=14,7/10%=147g
mdd sau pứ=2,7+147-0,15.2=149,4g
C%dd Al2(SO4)3=17,1/149,4.100%=11,45%
a, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=0,2.1,35=0,27\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{2}>\dfrac{0,27}{3}\), ta được Al dư.
Theo PT: \(n_{H_2}=n_{H_2SO_4}=0,27\left(mol\right)\Rightarrow V_{H_2}=0,27.22,4=6,048\left(l\right)\)
b, \(n_{Al\left(pư\right)}=\dfrac{2}{3}n_{H_2SO_4}=0,18\left(mol\right)\)
\(\Rightarrow m_{Al\left(pư\right)}=0,18.27=4,86\left(g\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}=0,09\left(mol\right)\)
\(\Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,09}{0,2}=0,45\left(M\right)\)
n hh khí = 0.5 mol
nCO: x mol
nCO2: y mol
=> x + y = 0.5
28x + 44y = 17.2 g
=> x = 0.3 mol
y = 0.2 mol
Khối lượng oxi tham gia pứ oxh khử oxit KL: 0.2 * 16 = 3.2g => m KL = 11.6 - 3.2 = 8.4g
TH: KL hóa trị I => nKL = 2*nH2 = 0.3 mol => KL: 28!!
KL hóa trị III => nKL = 2/3 *nH2 = 0.1 mol => KL: 84!!
KL hóa trị II => nKL = nH2 = 0.15 mol => KL: 56 => Fe.
nFe / Oxit = 0.15 mol
nO/Oxit = 0.2 mol
=> nFe/nO = 3/4 => Fe3O4
Fe3O4 + 4CO = 3Fe + 4CO2
Fe + H2SO4 = FeSO4 + H2
0.15.....0.15.......0.15.....0.15
=> mH2SO4 pứ = 14.7 g => mdd = 147 g
m dd sau khi cho KL vào = m KL + m dd - mH2 thoát ra = 0.15 * 56 + 147 - 0.15*2 = 155.1g
=> C% FeSO4 = 14.7%
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)
c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)
d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
PTHH: 2Na+2H2O=>2 NaOH+H2
nH2SO4=0,2mol
PTHH: 2NaOH+H2SO4=> Na2SO4+2H2O
0,4mol<-0,2mol
=> n NaOH=0,4mol
mà nNaOH=nNa=0,4mol
=> m Na =0,4.23=9,2g
nH2=1/2nNaOH=1/2.0,2=0,1mol
=> V H2=0,1.22,4=2,24ml
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot29,4\%}{98}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,6}{3}\) \(\Rightarrow\) Axit còn dư, Nhôm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,6-0,3=0,3\left(mol\right)\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72 \left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=204,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}\cdot100\%\approx16,7\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{204,8}\cdot100\%\approx14,36\%\end{matrix}\right.\)
Cho mình hỏi chút. Bài 1 sao C% = 2 vậy. Mình tưởng C%= 98 chứ nhỉ?
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.24,79=7,437\left(l\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=1,5.0,2=0,3mol\\ V_{H_2}=0,3.24,79=7,437l\)