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a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
4) x,y lần lượt là số mol của M và M2O3
=> nOxi=3y=nCO2=0,3 => y=0,1
Đề cho x=y=0,1 =>0,1M+0,1(2M+48)=21,6 =>M=56 => Fe và Fe2O3
=> m=0,1.56 + 0,1.2.56=16,8
2)X + 2HCl === XCl2 + H2
n_h2 = 0,4 => X = 9,6/0,4 = 24 (Mg)
=>V_HCl = 0,4.2/1 = 0,8 l
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
n hh khí = 0.5 mol
nCO: x mol
nCO2: y mol
=> x + y = 0.5
28x + 44y = 17.2 g
=> x = 0.3 mol
y = 0.2 mol
Khối lượng oxi tham gia pứ oxh khử oxit KL: 0.2 * 16 = 3.2g => m KL = 11.6 - 3.2 = 8.4g
TH: KL hóa trị I => nKL = 2*nH2 = 0.3 mol => KL: 28!!
KL hóa trị III => nKL = 2/3 *nH2 = 0.1 mol => KL: 84!!
KL hóa trị II => nKL = nH2 = 0.15 mol => KL: 56 => Fe.
nFe / Oxit = 0.15 mol
nO/Oxit = 0.2 mol
=> nFe/nO = 3/4 => Fe3O4
Fe3O4 + 4CO = 3Fe + 4CO2
Fe + H2SO4 = FeSO4 + H2
0.15.....0.15.......0.15.....0.15
=> mH2SO4 pứ = 14.7 g => mdd = 147 g
m dd sau khi cho KL vào = m KL + m dd - mH2 thoát ra = 0.15 * 56 + 147 - 0.15*2 = 155.1g
=> C% FeSO4 = 14.7%
a, \(m_{HCl}=150.7,3\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Theo PT: \(n_{Mg}=n_{MgCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\)
\(m_{Mg}=0,15.24=3,6\left(g\right)\)
b, \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c, Ta có: m dd sau pư = 3,6 + 150 - 0,15.2 = 153,3 (g)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,15.95}{153,3}.100\%\approx9,3\%\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.................................0.1\)
\(Đặt:n_{CuO\left(pư\right)}=x\left(mol\right)\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(x............x\)
\(m_{cr}=6-80x+64x=5.2\left(g\right)\)
\(\Rightarrow x=0.05\)
\(H\%=\dfrac{0.05}{0.075}\cdot100\%=66.67\%\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
PTHH:
\(Zn+2HCl-->ZnCl_2+H_2\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a) \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{H_2}=0,1.2=0,2\left(mol\right)\)
b) \(n_{HCl}=2n_{Zn}=2.0,1=0,2\left(mol\right)\)
=>\(C_M=\dfrac{0,1}{0,6}=0,167\left(M\right)\)
c) PTHH:
\(FeO+H_2-->Fe+H_2O\)
\(n_{FeO}=\dfrac{32}{72}=0,45\left(mol\right)\)
Theo PT:
\(n_{FeO}=n_{H_2}=0,1< 0,45\left(mol\right)\)
=>FeO dư => \(n_{FeO_{\left(dư\right)}}=0,45-0,1=0,35\left(mol\right)\)
=>\(m_{FeO_{\left(dư\right)}}=0,35.72=25,2\left(g\right)\) (1)
=> \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\) => \(m_{Fe}=0,1.56=5,6\left(g\right)\) (2)
Cộng (1) vs (2) => \(m_{chấtrắn}=25,2+5,6=30,8\left(g\right)\)