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Câu 1 :
\(n_{H2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)
Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
a 0,15 1,5a
\(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
b 0,3 1b
a) Gọi a là số mol của Al
b là số mol của Zn
\(m_{Al}+m_{Zn}=11,1\left(g\right)\)
⇒ \(n_{Al}.M_{Al}+n_{Zn}.M_{Zn}=11,1g\)
⇒ 27a + 65b = 11,1g(1)
Theo phương trình : 1,5a + 1b = 0,225(2)
Từ(1),(2), ta có hệ phương trình :
27a + 65b = 11,1g
1,5a + 1b = 0,225
⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,15\end{matrix}\right.\)
\(m_{Al}=0,05.27=1,35\left(g\right)\)
\(m_{Zn}=0,15.65=9,75\left(g\right)\)
0/0Al = \(\dfrac{1,35.100}{11,1}=12,16\)0/0
0/0Zn = \(\dfrac{9,75.100}{11,1}=87,84\)0/0
b) \(n_{HCl\left(tổng\right)}=0,15+0,3=0,45\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,45}{1}=0,45\left(l\right)\)
Chúc bạn học tốt
Câu 2 :
\(n_{H2}=\dfrac{1,456}{22,4}=0,065\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
a 0,1 1a
\(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
b 0,03 1,5b
a) Gọi a là số mol của Fe
b là số mol của Al
\(m_{Fe}+m_{Al}=3,07\left(g\right)\)
⇒ \(n_{Fe}.M_{Fe}+n_{Al}.M_{Al}=3,07g\)
⇒ 56a + 27b = 3,07g(1)
Theo phương trình : 1a + 1,5b = 0,065(2)
Từ(1),(2),ta có hệ phương trình :
56a + 27b = 3,07g
1a + 1,5b = 0,065
⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,01\end{matrix}\right.\)
\(m_{Fe}=0,05.56=2,8\left(g\right)\)
\(m_{Al}=0,01.27=0,27\left(g\right)\)
0/0Fe = \(\dfrac{2,8.100}{3,07}=91,21\)0/0
0/0Al = \(\dfrac{0,27.100}{3,07}=8,79\)0/0
b) \(n_{HCl\left(tổng\right)}=0,1+0,03=0,13\left(mol\right)\)
\(m_{HCl}=0,13.36,5=4,745\left(g\right)\)
\(m_{ddHCl}=\dfrac{4,745.100}{10}=47.45\left(g\right)\)
Chúc bạn học tốt
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
a) Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_{Zn}\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,4\cdot65}{36,2}\cdot100\%\approx71,23\%\) \(\Rightarrow\%m_{Al_2O_3}=28,77\%\)
c) Ta có: \(n_{Al_2O_3}=\dfrac{36,2-0,4\cdot65}{102}=0,1\left(mol\right)\)
Theo PTHH: \(n_{HCl}=2n_{Zn}+6n_{Al_2O_3}=1,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{1,4\cdot36,5}{10\%}=511\left(g\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{511}{1,1}\approx464,5\left(ml\right)=0,4645\left(l\right)\)
c) Theo PTHH: \(\left\{{}\begin{matrix}n_{ZnCl_2}=0,4\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,4}{0,4645}\approx0,86\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4645}\approx0,43\left(M\right)\end{matrix}\right.\)
a) Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow24a+27b=5,1\) (1)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Bảo toàn electron: \(2a+3b=0,5\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%\approx47,06\%\\\%m_{Al}=52,94\%\end{matrix}\right.\)
b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\)
\(\Rightarrow V_{HCl}=\dfrac{250}{1,2}\approx208,33\left(ml\right)\)
\(n_{H_2}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=27,8\\1,5a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\\ a,\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%=19,424\%\\\Rightarrow\%m_{Fe}=80,576\%\\ b,n_{HCl}=3a+2b=1,4\left(mol\right)\\ m_{ddHCl}=\dfrac{1,4.36,5.100}{20}=255,5\left(g\right) \Rightarrow4\approx\approx\approx\Rightarrow FeHCm=\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)
PTHH: Zn + 2HCl --> ZnCl2 + H2
Fe + 2HCl --> FeCl2 + H2
2Al + 6HCl --> 2AlCl3 + 3H2
=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)
PTHH: Zn + Cl2 --to--> ZnCl2
2Fe + 3Cl2 --to--> 2FeCl3
2Al + 3Cl2 --to--> 2AlCl3
=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)
(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)
b) nHCl = 2a + 2b + 3c = 0,45 (mol)
=> mHCl = 0,45.36,5 = 16,425 (g)
=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)
c) mdd sau pư = 10,65 + 200 - 0,225.2 = 210,2 (g)
=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)
Gọi số mol Al, Fe là a, b
\(m_{Cu}=m_B=6,4\left(g\right)\)
=> \(m_{Al}+m_{Fe}=17,4-6,4=11\left(g\right)\)
=> 27a + 56b = 11
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
b----------------------->b
2Al + 6HCl --> 2AlCl3 + 3H2
a------------------------>1,5a
=> 1,5a + b = 0,4
=> a = 0,2; b = 0,1
=> \(\left\{{}\begin{matrix}m_{Fe}=0,1.56=5,6\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)