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Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)
Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
pthh: Zn+H2SO4→ZnSO4+H2 (1)
ZnO+H2SO4→ZnSO4+H2O (2)
n H2=0,2 (mol)
theo pt1 ta có nZn=nH2=0,2 (mol)
⇒ mZn=0,2 .65=13 (g)→mZnO=21,1-13=8,1 (g) →nZnO=0,1 (mol)
Theo pt 1 nH2SO4=nZn=0,2(mol) (3)
Theo pt2 nH2SO4=nZnO=0,2 (mol) (4)
Từ 3,4 ⇒nHCl=0,4 (mol)
V H2SO4=0,4\1=0,4l =400ml
a, Ta có : \(n_{CO2}=\dfrac{V}{22,4}=0,1\left(mol\right)\)
\(BTNT\left(C\right):n_{MgCO3}=n_{CO2}=0,1\left(mol\right)\)
\(\Rightarrow m_{MgCO3}=n.M=8,4\left(g\right)\)
\(\Rightarrow m_{MgO}=8\left(g\right)\)
b, Thấy sau khi phản ứng xảy ra thu được dung dịch A gồm \(MgSO_4\) và có thể còn \(H_2SO_4\) dư .
\(BTNT\left(Mg\right):n_{MgSO_4}=n_{MgCO3}+n_{MgO}=0,3\left(mol\right)\)
\(PTHH:MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2\downarrow+BaSO_4\downarrow\)
.................0,3............0,3..................0,3..................0,3.............
\(\Rightarrow m_{\downarrow}=m_{Mg\left(OH\right)2}+m_{BaSO4}=87,3\left(g\right)\)
Mà \(\left\{{}\begin{matrix}m\downarrow=110,6\left(g\right)>87,3g\\n_{Ba\left(OH\right)2}=C_M.V=0,45>n_{Ba\left(OH\right)2pu}\left(0,3mol\right)\end{matrix}\right.\)
=> Dung dịch A vẫn còn H2SO4 dư và mol BaSO4 được tạo ra tiếp là :
\(n_{BaSO4}=\dfrac{110,6-87,3}{M}=0,1\left(mol\right)\)
\(PTHH:H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)
..................0,1............0,1...............0,1........................
Lại có : \(n_{Ba\left(OH\right)2}=0,45\left(mol\right)\)
=> Trong dung dịch B còn có Ba(OH)2 dư ( dư 0,45 - 0,3 - 0,1 = 0,05mol)
\(\Rightarrow C_{MBa\left(OH\right)2}=\dfrac{n}{V}=\dfrac{0,05}{0,5}=0,1\left(M\right)\)
Vậy ...
C32:
a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)
PT: \(C+O_2\underrightarrow{t^o}CO_2\)
Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ mNaHCO3 = 0,1.84 = 8,4 (g)
mNa2CO3 = 0,1.106 = 10,6 (g)
c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)
Lần sau bạn đăng tách câu hỏi ra nhé.
C31:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)
c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)
PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\left(1\right)\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\left(2\right)\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT (1): \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=m_{hh}-m_{Mg}=4,4-2,4=2\left(g\right)\)
Bạn tham khảo nhé!
Fe + 2HCl -> FeCl2 + H2
0.2 0.1
FeO + 2HCl -> FeCl2 + H2O
0.1 0.2
a.\(nH2=\dfrac{2.24}{22.4}=0.1mol\)
\(\%mFe=\dfrac{0.1\times56\times100}{12.8}=43.8\%\)
\(\%mFeO=100-43.8=56.2\%\)
b.\(nFeO=\dfrac{12.8-\left(0.1\times56\right)}{56+16}=0.1mol\)
\(V_{HCl}=\dfrac{0.2+0.2}{2}=0.2l\)
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
tích đúng đê
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2|\)
1 1 1 1
0,1 0,1 0,1
\(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O|\)
1 1 1 1
0,1 0,1
a) \(n_{Zn}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Zn}=0,1.65=6,5\left(g\right)\)
\(m_{ZnO}=14,6-6,5=8,1\left(g\right)\)
b) Có : \(m_{MgO}=8,1\left(g\right)\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(n_{H2SO4\left(tổng\right)}=0,1+0,1=0,2\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Chúc bạn học tốt