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\(n_{Al}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PTHH: Al2O3 + 6HNO3 ---> 2Al(NO3)3 + 3H2O
0,1 0,6 0,2 0,3
\(\rightarrow m_{HNO_3}=0,6.63=37,8\left(g\right)\\ m_{ddHNO_3}=\dfrac{37,8}{15\%}=252\left(g\right)\\ m_{dd\left(sau.pư\right)}=252+10,2=262,2\left(g\right)\\ m_{Al\left(NO_3\right)_3}=0,2.213=42,6\left(g\right)\\ C\%_{Al\left(NO_3\right)_3}=\dfrac{42,6}{262,2}=16,25\%\)
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\\ a,2K+2H_2O\rightarrow2KOH+H_2\uparrow\\ n_{H_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\\ V_{H_2\left(\text{đ}ktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,n_{KOH}=n_K=0,2\left(mol\right)\\ m_{KOH}=0,2.56=11,2\left(g\right)\\ c,m_{\text{dd}sau}=m_K+m_{H_2O}-m_{H_2}\)
Nhưng chưa có KL nước?
n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)
n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)
\(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
bđ 0,1............0,5
pư 0,1............0,3..................0,1
spu 0 ................0,2................0,1
=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O
m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)
m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)
m dd = \(490+10,2=500,2g\)
% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)
% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
$n_{Al_2O_3} = 10,2 : 102 = 0,1(mol)$
$n_{HCl} = 0,35.2 = 0,7(mol)$
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
Ban đầu : 0,1 0,7 (mol)
Phản ứng: 0,1 0,6 (mol)
Sau pư : 0 0,1 0,2 (mol)
A gồm HCl, $AlCl_3$
$C_{M_{HCl\ dư}} = \dfrac{0,1}{0,35} = 0,285M$
$C_{M_{AlCl_3}} = \dfrac{0,2}{0,35} = 0,571M$
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
a, Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=1,2\left(mol\right)\)
\(\Rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\)
b, Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\)
\(Al_2O_3+HCl\rightarrow AlCl_3+H_2O\)
\(m_{Al_2O_3}=10,2g\)
_______________________________
\(m_{AlCl_3}=?;m_{H_2O}?\)
Bài làm
\(n_{AL_2O_3}=\dfrac{m}{M}=\dfrac{10,2}{2.27+3.16}=0,1\left(mol\right)\)
Theo PTHH :
\(n_{AlCl_3}=n_{H_2O}=n_{Al_2O_3}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=n.M=0,1.\left(27+3.35,5\right)=6,25\left(g\right)\\m_{H_2O}=n.M=0,1.\left(2.1+16\right)=1,8\left(g\right)\end{matrix}\right.\)
Sorry bn ,gửi bài r mk ms kiểm tra lại ,mk chưa cân bằng phương trình nha bn,bh mk cân bằng xg r lm tương tự nha bn
\(AL_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)