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\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.24,79=7,437\left(l\right)\)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4-->0,6---------->0,2------->0,6
=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)
b) VH2 = 0,6.22,4 = 13,44 (l)
c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\
pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,4 0,6 0,2 0,6
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\)
\(C_M=\dfrac{0,2}{0,15}=1,3M\)
$a) 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$b) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)$
Theo PTHH : $n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,6(mol)$
$m_{H_2SO_4} = 0,6.98 = 58,8(gam)$
$c) n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol) \Rightarrow m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)$
$d) n_{H_2} = n_{H_2SO_4} = 0,6(mol) \Rightarrow V_{H_2} = 0,6.22,4 = 13,44(lít)$
\(a,2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(b.n_{Al}=\dfrac{m}{M}=0,4\left(mol\right)\)
\(Theo.PTHH\Rightarrow n_{H_2SO_4}=n_{H_2}=\dfrac{3}{2}n_{Al}=1,5.0,4=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=n.M=0,6.98=58,8\left(g\right)\)
\(c,Theo.PTHH\Rightarrow n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,5.0,4=0,2\left(mol\right)\\ \Rightarrow m_{Al_2\left(SO_4\right)_3}=n.M=0,2.342=68,4\left(g\right)\\ d,V_{H_2\left(dktc\right)}=n.22,4=0,6.22,4=13,44\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot29,4\%}{98}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,6}{3}\) \(\Rightarrow\) Axit còn dư, Nhôm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,6-0,3=0,3\left(mol\right)\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72 \left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=204,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}\cdot100\%\approx16,7\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{204,8}\cdot100\%\approx14,36\%\end{matrix}\right.\)
\(a,PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow\text{Số nguyên tử Al là }2\\ b,n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,2\left(mol\right)\\ \Rightarrow m_{Al_2\left(SO_4\right)_3}=0,2\cdot342=68,4\left(g\right)\\ c,C_1:n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ C_2:n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\\ \Rightarrow m_{Al}=0,4\cdot27=10,8\left(g\right)\\ m_{H_2}=0,6\cdot2=1,2\left(g\right)\\ \text{Bảo toàn KL: }m_{H_2SO_4}=m_{Al_2\left(SO_4\right)_3}+m_{H_2}-m_{Al}=68,4+1,2-10,8=58,8\left(g\right)\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)
c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)
d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
2) PTHH
2Al + 3H2SO4 ➝ Al2(SO4)3 + 3H2
2mol 3mol 1mol 3mol
0,2mol 0,3mol 0,1mol 0,3mol
- nAl = 5,4/27= 0,2 mol
a) m Al2(SO4)3 = 0,1. 342=34,2 g
b) V H2 = 0,3 . 22,4 = 6,72 lít
c) m H2SO4= 0,3 . 98=29,4 g
C% dd H2SO4 = 29,4/200 . 100= 14,7 %