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Do quặng chứa 10% tạp chất
=> FeS2 chiếm 90%
\(m_{FeS_2}=\dfrac{125.90}{100}=112,5\left(g\right)\)
=> \(n_{FeS_2}=\dfrac{112,5}{120}=0,9375\left(mol\right)\)
PTHH: 4FeS2 + 11O2 --to--> 2Fe2O3 + 8SO2
0,9375---------------------->1,875
=> VSO2 = 1,875.22,4 = 42 (l)
\(a) n_{O_2} = \dfrac{2,24}{22,4} = 0,1(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{Fe} = \dfrac{3}{2}n_{O_2} = 0,15(mol)\\ m_{Fe} = 0,15.56 = 8,4(gam)\\ b) \%Fe = \dfrac{56.3}{56.3+16.4}.100\% = 72,41\% \%O = 100\% - 72,41\% = 27,59\%\\ c) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,2(mol)\\ m_{KMnO_4} = 0,2.158 = 31,6(gam)\)
\(n_{O_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(0.15.......0.1......0.05\)
\(m_{Fe_3O_4}=0.05\cdot232=11.6\left(g\right)\)
\(\%Fe=\dfrac{0.05\cdot3\cdot56}{11.6}\cdot100\%=72.41\%\)
\(\%O=10072.41=27.59\%\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.2...................................................0.1\)
\(m_{_{ }KMnO_4}=0.2\cdot158=31.6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
Bài 3 :
PTHH : \(6Fe+4O_2\left(t^o\right)->2Fe_3O_4\) (1)
\(n_{Fe_3O_4}=\dfrac{m}{M}=\dfrac{2,32}{56.3+16.4}=0,01\left(mol\right)\)
Từ (1) => \(3n_{Fe_3O_4}=n_{Fe}=0,03\left(mol\right)\)
=> \(m_{Fe}=n.M=1,68\left(g\right)\)
Từ (1) => \(2n_{Fe_3O_4}=n_{O_2}=0,02\left(mol\right)\)
=> \(V_{O_2\left(đktc\right)}=n.22,4=0,448\left(l\right)\)
Bài 4 :
PTHH : \(4P+5O_2\left(t^o\right)->2P_2O_5\) (1)
\(n_P=\dfrac{m}{M}=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{32}=0,21\left(mol\right)\)
Có : \(n_P< n_{O_2}\left(0,2< 0,21\right)\)
-> P hết ; O2 dư
Từ (1) -> \(\dfrac{1}{2}n_P=n_{P_2O_5}=0,1\left(mol\right)\)
=> \(m_{P_2O_5}=n.M=14,2\left(g\right)\)
Bài 3:
\(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,03 0,02 0,01
\(m_{Fe}=0,03.56=1,68\left(g\right);V_{O_2}=0,02.22,4=0,448\left(l\right)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{Fe}=3n_{Fe_3O_4}=0,06\left(mol\right)\\n_{O_2}=2n_{Fe_3O_4}=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{Fe}=0,06.56=3,36\left(g\right)\)
\(m_{O_2}=0,04.32=1,28\left(g\right)\)
b, Phần này đề bài cho là KMnO4 hay KClO3 vậy bạn?
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PT: 3Fe + 2O2 ➝ Fe3O4
mol 0,15 ➝ 0,05
\(m_{Fe_3O_4}=0,05.232=11,6\left(g\right)\)
Số sắt nguyên chất là: 168.(100% - 20%) = 134,4(g)
\(n_{Fe}=\dfrac{134,4}{56}=2,4\left(mol\right)\)
PT: 3Fe + 2O2 ➝ Fe3O4
mol 2,4 ➝ 1,6
\(V_{O_2\left(đktc\right)}=1,6.22,4=35,84\left(l\right)\)