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`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `0,1` `(mol)`
`n_[HCl]=0,2.1=0,2(mol)`
`=>m_[Zn]=0,1.65=6,5(g)`
`b)m_[dd HCl]=1,1.200=220(g)`
`=>C%_[ZnCl_2]=[0,1.136]/[6,5+220-0,1.2].100~~6%`
\(a,n_{HCl}=0,2.1=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,1<--0,2------>0,1------->0,1
\(\rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(b,m_{ddHCl}=200.1,1=220\left(g\right)\)
\(\rightarrow m_{dd}=220+6,5-0,1.2=226,3\left(g\right)\\ \rightarrow C\%_{ZnCl_2}=\dfrac{0,1.136}{226,3}.100\%=6\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
`a)PTHH:`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,3` `0,6` `0,3` `0,3` `(mol)`
`n_[Fe]=[22,4]/56=0,4(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
Ta có:`[0,4]/1 > [0,6]/2`
`=>Fe` dư
`b)m_[FeCl_2]=0,3.127=38,1(g)`
`c)m_[Fe(dư)]=(0,4-0,3).56=5,6(g)`
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Xét: \(\dfrac{0,4}{1}>\dfrac{0,6}{2}\) ( mol )
0,3 0,6 0,3 ( mol )
\(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)
\(m_{Fe\left(dư\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)
a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
\(a) Fe + 2HCl \to FeCl_2\\ b) n_{HCl} = \dfrac{182,5.5\%}{36,5} = 0,25(mol)\\ n_{FeCl_2} = n_{H_2} = n_{Fe} = \dfrac{1}{2}n_{HCl} = 0,125(mol)\\ \Rightarrow m_{Fe} = 0,125.56 = 7(gam) ; V = 0,125.22,4 = 2,8(lít)\\ c) m_{dd\ sau\ phản\ ứng} = m_{Fe} + m_{dd\ HCl} - m_{H_2} = 7 + 182,5 - 0,125.2 = 189,25(gam)\\ C\%_{FeCl_2} = \dfrac{0,125.127}{189,25}.100\% = 8,39\%\)
Fe+2HCl->FeCl2+H2
0,125--0,25---0,125-0,125
m HCl=9,125 g=>n HCl=\(\dfrac{9,125}{26,5}\)=0,25 mol
=>m Fe=0,125.56=7g
=>VH2=0,125.22,4=2,8l
=>C%FeCl2=\(\dfrac{0,125.127}{7+182,5-0,25}\).100=8,388%
`n_[Zn]=13/65=0,2(mol)`
`Zn + 2HCl -> ZnCl_2 + H_2 \uparrow`
`0,2` `0,4` `0,2` `(mol)`
`a)V_[H_2]=0,2.22,4=4,48(l)`
`b)C%_[HCl]=[0,4.36,5]/150 .100~~9,73%`
ta có: nHCl= V. CM= 0,1. 2= 0,2( mol)
PTPU
Fe+ 2HCl---> FeCl2+ H2
0,1....0,2...........0,1...0,1...
=> mFe= 0,1. 56= 5.6( g)
ta có: mHCl= V. D= 1,1. 100= 110( g)
ADĐLBTKL ta có
mmuối= mFe+ mHCl- mH2
=5,6+ 110- 0,1. 2
= 115,4( g)
=> C%FeCl2= \(\dfrac{mct}{mdd}\)= \(\dfrac{0,1.127}{115,4}\). 100%\(\approx\)11, 01%
nFe = 0,1 . 2 = 0,2 mol
Fe +2 HCl -> FeCl2 + H2
0,2mol->0,4mol -> 0,2mol
mFe = 0,2 . 56 =11,2g
VH2 = 0,2.22,4 = 4,48 l
mct = 0, 4 . 36,5 = 14,6 g
mdd = 100. 1,1 = 110 g
=> C% = \(\dfrac{14,6}{110}\) . 100% = 13,27%