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\(n_{Zn}=\frac{6,5}{65}=0,1\left(mol\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,1_______0,1____________0,1______________
\(m_{muoi}=0,1.\left(12+3+12+16+16\right).2+65=18,3\left(g\right)\)
\(\Rightarrow V_{H2}=0,1.22,4=2,24\left(l\right)\)
Zn+CH3COOH--->H2+(CH3COO)2Zn
n Zn=6,5/65=0,1(mol)
n H2=n Zn=0,1(mol)
V H2=0,1.22,4=2,24(l)
n (CH3COO)2Zn=n Zn=0,1(mol)
m (CH3COO)2Zn=0,1.183=18,3(g)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
\(a,PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ b,n_{FeCl_2}=n_{H_2}=n_{Fe}=0,4\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ c,m_{FeCl_2}=127.0,4=50,8\left(g\right)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
Rượu etylic \(C_2H_5OH\)
Axit axetic \(CH_3COOH\)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)
0,2 0,1 0,2 0,1 0,1
\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)
\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)
a)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
0,2<----------0,1<-------------0,2<-------0,1
=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)
\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)
b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)
\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)
Bài 14 :
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,15 0,3 0,15 0,15
a) \(n_{H2}=\dfrac{0,15.1}{1}=0,15\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,15.2}{1}=0,3\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c) \(n_{FeCl2}=\dfrac{0,15.1}{1}=0,15\left(mol\right)\)
\(C_{M_{FeCl2}}=\dfrac{0,15}{0,15}=1\left(M\right)\)
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Zn+2CH3OOH---->H2+(CH3OO)2Zn
n Zn=6,5/65=0,1(mol)
n H2=n Zn=0,1(mol)
V H2=0,1.22,4=2,24(l)
n (CH3OO)2Zn=n Zn=0,1(mol)
m (CH3OO)2Zn=0,1.159=15,9(g)
\(n_{Zn}=\frac{6,5}{65}=0,1\left(mol\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,1___________________0,1________0,1
\(m_{muoi}=0,1.\left(12+3+12+16+16\right).2+65=18,3\left(g\right)\)
\(\Rightarrow V_{H2}=0,1.22,4=2,24\left(l\right)\)