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a, \(CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)
\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
b, Ta có: \(n_{NaOH}=0,2.0,5=0,1\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=n_{NaOH}=0,1\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}+\dfrac{1}{2}n_{C_2H_5OH}=0,3\)
\(\Rightarrow n_{C_2H_5OH}=0,5\left(mol\right)\)
\(\Rightarrow m=m_{CH_3COOH}+m_{C_2H_5OH}=0,1.60+0,5.46=29\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,1.60}{29}.100\%\approx20,69\%\\\%m_{C_2H_5OH}\approx79,31\%\end{matrix}\right.\)
2C2H5OH+Na->2C2H5ONa +H2
0,3------------------------------------0,15
2CH3COOH+Na->2CH3COONa+H2
0,1-------------------------------------->0,05
NaOH+CH3COOH->CH3COONa+H2O
0,1-------0,1 mol
n khí =4,48 \22,4=0,2 mol
n NaOH=0,5.0,2=0,1 mol
=>nH2 pt2=0,05
=>n H2 pt1=0,15
=>mC2H5OH=0,3.46=13,8g
=>m CH3COOH=0,1.60=6g
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$
b)
Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$
$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$
c) $Fe + CuSO_4 \to FeSO_4 + Cu$
$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$
$= 3,6 + 0,15.64 = 13,2(gam)$
\(n_{CO_2}=\dfrac{0,448}{22,4}=0,02(mol)\\ a,CaCO_3+2HCl\to CaCl_2+H_2O+CO_2\uparrow\\ b,n_{CaCO_3}=n_{CO_2}=0,02(mol)\\ \Rightarrow m_{CaCO_3}=0,02.100=2(g)\\ c,\%_{CaCO_3}=\dfrac{2}{5}.100\%=40\%\\ \%_{CaSO_4}=100\%-40\%=60\%\)
a) PTHH: Fe + 2HCl ===> FeCl2 + H2
MgO + 2HCl ===> MgCl2 + H2O
b) Ta có: nH2 =\(\frac{2,24}{22,4}=0,1\left(mol\right)\)
=> nFe = nH2 = 0,1 (mol)
=> mFe = 0,1 x 56 = 5,6 gam
=> mMgO = 22,4 - 5,6 = 156,8 gam
c. %MgO = \(\frac{16,8}{22,4}.100\%=75\%\)
=> %Fe = 100% - 75% = 25%
\(n_{NaOH}=\dfrac{4}{40}=0,1\left(mol\right)\)
PTHH : \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
0,1 0,1
\(C_2H_5OH+NaOH\rightarrow ko.p.ứng\)
\(\%_{m_{CH_3COOH}}=\dfrac{0,1.60}{40}.100=15\%\\ \Rightarrow\%_{m_{C_2H_5OH}}=100\%-15\%=85\%\)