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a, \(n_{CO_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(MgO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2O\)
\(MgCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+CO_2+H_2O\)
Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,1.84}{10,4}.100\%\approx80,77\%\\\%m_{MgO}\approx19,23\%\end{matrix}\right.\)
b, \(n_{MgO}=\dfrac{10,4-0,1.84}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{MgO}+2n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
a)
$CH_3COOH + NaHCO_3 \to CH_3COONa + CO_2 + H_2O$
b)
n NaHCO3 = n CH3COOH = 100.12%/60 = 0,2(mol)
m dd NaHCO3 = 0,2.84/8% = 210(gam)
c)
n CO2 = n CH3COOH = 0,2(mol)
=> V CO2 = 0,2.22,4 = 4,48(lít)
d)
m dd = m dd CH3COOH + m dd NaHCO3 - m CO2 = 100 + 210 - 0,2.44 = 301,2(gam)
C% CH3COONa = 0,2.82/301,2 .100% = 5,44%
Ta có: \(n_{NaOH}=0,1.0,5=0,05\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{CH_3COONa}=n_{NaOH}=0,05\left(mol\right)\)
a, \(C_{M_{CH_3COOH}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
b, \(m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
a)
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15<---------0,3<------------------------0,15
=> \(C\%_{dd.CH_3COOH}=\dfrac{0,3.60}{200}.100\%=9\%\)
b)
\(m_{dd.Na_2CO_3}=\dfrac{0,15.106.100}{15}=106\left(g\right)\)
c)
PTHH: 2CH3COOH + Ba(OH)2 --> (CH3COO)2Ba + 2H2O
0,3--------->0,15
=> \(V_{dd.Ba\left(OH\right)_2}=\dfrac{0,15}{0,5}=0,3\left(l\right)=300\left(ml\right)\)
\(a) n_{CH_3COOH} = \dfrac{200.12\%}{60} = 0,4(mol)\\ 2CH_3COOH + CaCO_3 \to (CH_3COO)_2Ca + CO_2 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_3COOH} = 0,2(mol)\\ \Rightarrow a = \dfrac{0,2.100}{100\%-20\%} =25(gam)\\ V_B = 0,2.22,4 = 4,48(lít)\\ b) m_{dd\ sau\ pư} = m_{CaCO_3} + m_{dd\ CH_3COOH} - m_{CO_2} = 0,2.100 + 200 - 0,2.2 = 219,6(gam)\\ C\%_{(CH_3COO)_2Ca} = \dfrac{0,2.158}{219,6}.100\% = 36\%\)
\(n_{Fe}=\dfrac{6,5}{56}=\dfrac{13}{112}mol\)
\(m_{CH_3COOH}=\dfrac{90\cdot20\%}{100\%}=18g\Rightarrow n_{CH_3COOH}=0,3mol\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\uparrow\)
\(\dfrac{13}{112}\) 0,3 0 0
\(\dfrac{13}{112}\) \(\dfrac{13}{56}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
0 \(\dfrac{19}{280}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
a)\(m_{\left(CH_3COO\right)_2Fe}=\dfrac{13}{112}\cdot174=20,2g\)
\(m_{H_2}=\dfrac{13}{112}\cdot2=\dfrac{13}{56}g\)
\(m_{dd\left(CH_3COO\right)_2Fe}=6,5+90-\dfrac{13}{56}=96,27g\)
\(C\%=\dfrac{20,2}{96,27}\cdot100\%=20,98\%\)
Giả sử có 100g dd CH3COOH 15%
Ta có:
nCH3COOH=\(\dfrac{100.15\%}{60}\)=0,25(mol)
PTHH:Ca(OH)2+2CH3COOH→(CH3COO)2Ca+2H2O
⇒nCa(OH)2=n(CH3COO)2Ca=0,125(mol)
⇒mdd(Ca(OH)2)=\(\dfrac{0,125.74}{X\%}\)=9,25
⇒mdd(spu)=\(\dfrac{9,25}{X\%+100}\)⇔C%=9,875%
\(\dfrac{0,125.158.100}{\dfrac{9,25}{X\%+100}}\)=9,875⇔x=9,25
CH3COOH + NaHCO3 \(\rightarrow\) CH3COONa + H2O + CO2\(\uparrow\) (1)
a) Ta có: \(m_{NaHCO_3}=\dfrac{20\cdot500}{100}=100\left(g\right)\)
\(\Rightarrow n_{NaHCO_3}=\dfrac{100}{84}\approx1,2\left(mol\right)\)
Theo phương trình (1): \(n_{CH_3COOH}=n_{NaHCO_3}=1,2\left(mol\right)\)
\(\Rightarrow m_{CH_3COOH}=1,2\cdot60=72\left(g\right)\)
Do đó: \(C\%_{CH_3COOH}=\dfrac{72}{300}\cdot100\%=24\%\)