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\(a,n_{CaCO_3}=\dfrac{300}{100}=3mol\\ n_{HCl}=\dfrac{400.7,3}{100.36,5}=0,8mol\\ CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ \Rightarrow\dfrac{3}{1}>\dfrac{0,8}{2}\Rightarrow CaCO_3dư\\ n_{CaCl_2}=n_{CaCO_3}=n_{CO_2}=\dfrac{1}{2}\cdot0,8=0,4mol\\ m_{dd}=0,4.100+400-0,4.44=422,4g\\ C_{\%CaCl_2}=\dfrac{0,4.111}{422,4}\cdot100=10,51\%\)
\(c)n_{KOH}=\dfrac{200.11,2}{100.56}=0,4mol\\ T=\dfrac{0,4}{0,4}=1\\ \Rightarrow Tạo.KHCO_3\\ CO_2+KOH\rightarrow KHCO_3\\ n_{KHCO_3}=n_{CO_2}=0,4mol\\ m_{KHCO_3}=0,4.100=40g\)
a) $n_{CaCO_3} = 0,15(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{HCl} = 2n_{CaCO_3} = 0,3(mol)$
$m_{dd\ HCl} = \dfrac{0,3.36,5}{7,3\%} = 150(gam)$
b)
$n_{CaCl_2} = n_{CO_2} = n_{CaCO_3} =0,15(mol)$
$V_{CO_2} = 0,15.22,4 = 3,36(lít)$
c)
$m_{dd} = 15 + 150 - 0,15.44 = 158,4(gam)$
$C\%_{CaCl_2} = \dfrac{0,15.111}{158,4}.100\% = 10,51\%$
nH2=0.1(mol)
PTHH:Fe+H2SO4->FeSO4+H2
Fe2O3+3H2SO4->Fe2(SO4)3+3H2O
Theo pthh1:nFe=nH2->nFe=0.1(mol)
mFe=0.1*56=5.6(g)->%Fe=5.6:21.6*100=25.9%
%Fe2O3=100-25.9=74.1%
câu b câu c không liên quan đến đề bài bạn ơi,Chỉ có FeSO4,Fe2(SO4)3,và HCl thôi nhé,không có H2SO4 và MgSO4 đâu
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(\Rightarrow\left\{{}\begin{matrix}84\cdot n_{MgCO_3}+100\cdot n_{CaCO_3}=18,4\\n_{MgCO_3}+n_{CaCO_3}=n_{CO_2}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{MgCO_3}=0,1mol\\n_{CaCO_3}=0,1mol\end{matrix}\right.\)
\(\%m_{CaCO_3}=\dfrac{0,1\cdot100}{18,4}\cdot100\%=54,35\%\)
\(\%m_{MgCO_3}=100\%-54,35\%=45,65\%\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
a) nMg= 3,6/24=0,15(mol)
nHCl= (300.7,3%)/36,5= 0,6(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
Ta có: 0,15/1 < 0,6/2
=> HCl dư, Mg hết => Tính theo nMg.
nY=nH2=nMgCl2=nMg=0,15(mol)
=>V(Y,đktc)=V(H2,đktc)=0,15.22,4=3,36(l)
b) mMgCl2=0,15.95= 14,25(g)
nHCl(dư)= 0,6- 0,15.2=0,3(mol)
=>mHCl(dư)=0,3.36,5= 10,95(g)
mddsau= mMg + mddHCl - mH2= 3,6+ 300 - 0,15.2= 303,3(g)
=>C%ddHCl(dư)= (10,95/303,3).100= 3,610%
C%ddMgCl2= (14,25/303,3).100=4,698%
\(n_{HCl}=\dfrac{44,8}{22,4}=2\)
\(\Rightarrow m_{HCl}=2.36,5=73g\)
=> \(C\%_{HCl}=\dfrac{73}{73+327}\times100\%=18,25\%\)
b.
\(n_{HCl}=\dfrac{250.18,25\%}{36,5}=1,25mol\)
\(n_{CaCO_3}=\dfrac{50}{100}=0,5mol\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(n_{CaCl_2}=n_{CO_2}=0,5mol\)
\(n_{HClpu}=0,5.2=1mol\)
\(\Rightarrow n_{HCldu}=1,25-1=0,25\)
\(\Rightarrow m_{ddpu}=50+250-0,5.44=278g\)
\(C\%_{HCl}=\dfrac{0,25.36,5}{278}.100\%=3,28\%\)
\(C\%_{CaCl_2}=\dfrac{0,5.111}{278}.100\%=19,96\%\)
a, Ta có: \(n_{CaCO_3}=\dfrac{300}{100}=3\left(mol\right)\)
\(m_{HCl}=400.7,3\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{3}{1}>\dfrac{0,8}{2}\), ta được CaCO3 dư.
Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\)
b, Theo PT: \(n_{CaCO_3\left(pư\right)}=n_{CaCl_2}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\)
Ta có: m dd sau pư = 0,4.100 + 400 - 0,4.44 = 422,4 (g)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,4.111}{422,4}.100\%\approx10,51\%\)