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Ta có : \(m_{H_2SO_4}=14\%.200=28\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\frac{28}{98}=\frac{2}{7}\left(mol\right)\)
PTHH : \(2Al+3H_2SO_4=Al_2\left(SO_4\right)_3+3H_2\uparrow\)
(mol) 2/7 2/21
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\frac{2}{21}.342=\frac{228}{7}\left(g\right)\)
Ta có: mH\(_2\)SO\(_4\)= 200 . 14% = 28g
=> nH\(_2\)SO\(_4\)= 28/98 = 0,285 (mol)
PTHH : 3H\(_2\)SO\(_4\) + 2 Al ----> Al\(_2\)(SO\(_4\))\(_3\) + 3H\(_2\)
n H\(_2\)SO\(_4\)= 3nAl\(_2\)(SO\(_4\))\(_3\)
=> nAl\(_2\)(SO\(_4\))\(_3\)= 0,285 : 3 =0,095 (mol)
=> mAl\(_2\)(SO\(_4\))\(_3\)= 0,095 . 342 = 32,49 g
\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)
\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)
0,02 0,06
\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)
0,05 0,05
\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)
a) Sửa đề: dd H2SO4 9,8%
Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)
Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)
\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)
b) Tương tự câu a
\(2NaBr+Cl_2\rightarrow2NaCl+Br_2\left(1\right)\\ m_{giảm}=m_{Br_2}-m_{Cl_2}\\ \Leftrightarrow n_{NaCl\left(1\right)}=n_{NaBr\left(1\right)}=\dfrac{13,35}{160-71}=0,15\left(mol\right)\\ \Rightarrow\%m_{NaBr}=\dfrac{103.0,15}{42,6}.100\approx36,268\%\\ \Rightarrow\%m_{NaCl}\approx63,732\%\)
Bổ sung:
\(C\%_{ddNaBr\left(trongA\right)}=\dfrac{0,15.103}{200}.100=7,725\%\\ C\%_{ddNaCl\left(trongA\right)}=\dfrac{42,6-0,15.103}{200}.100=13,575\%\)
`2Fe + 6H_2 SO_[4(đ,n)] -> Fe_2(SO_4)_3 + 3SO_2 \uparrow + 6H_2 O`
`0,05` `0,15` `0,025` `(mol)`
`Cu + 2H_2 SO_[4(đ,n)] -> CuSO_4 + SO_2 \uparrow + 2H_2 O`
`0,225` `0,45` `0,225` `(mol)`
`n_[SO_2]=[6,72]/[22,4]=0,3(mol)`
Gọi `n_[Fe]=x` ; `n_[Cu]=y`
`=>` $\begin{cases} \dfrac{3}{2}x+y=0,3\\56x+64y=17,2 \end{cases}$
`<=>` $\begin{cases}x=0,05\\y=0,225 \end{cases}$
`@m_[Fe_2(SO_4)_3]=0,025.400=10(g)`
`@m_[CuSO_4]=0,225.160=36(g)`
`@m_[dd H_2 SO_4]=[(0,15+0,45).98]/80 .100=73,5(g)`
Sửa đề: 80% ---> 98% (80% chưa đặc nên không giải phóng SO2 được)
Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\end{matrix}\right.\)
\(\rightarrow56a+64b=17,2\left(1\right)\)
PTHH:
\(2Fe+6H_2SO_{4\left(đặc,nóng\right)}\rightarrow Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)
a------>3a------------------->0,5a--------------->1,5a
\(Cu+2H_2SO_{4\left(đặc,nóng\right)}\rightarrow CuSO_4+SO_2\uparrow+2H_2O\)
b----->2b------------------->b------------->b
\(\rightarrow1,5a+b=\dfrac{6,72}{22,4}=0,3\left(2\right)\)
Từ \(\left(1\right)\left(2\right)\rightarrow\left\{{}\begin{matrix}a=0,05\left(mol\right)\\b=0,225\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,5.0,05.400=10\left(g\right)\\m_{CuSO_4}=0,225.160=36\left(g\right)\\m_{ddH_2SO_4}=\dfrac{\left(0,05.3+0,225.2\right).98}{98\%}=60\left(g\right)\end{matrix}\right.\)
\(n_{Al_2\left(SO_4\right)_3}=\dfrac{3,42}{342}=0,01mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,03 0,01 ( mol )
\(V_{H_2SO_4}=\left(\dfrac{0,03}{0,04}\right)+0,1=0,85l\)
Câu 1 : Mk nghĩ đề thiếu rồi
Câu 2:
nFe2O3=0,3\(\rightarrow\)nFe=0,6
Sau toàn bộ quá trình thu được Fe2(SO4)3
nFe2(SO4)3=0,3
\(\rightarrow\)mFe2(SO4)3=120
