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Sửa lại câu c .
\(n_{H_2SO_4}=\dfrac{49.40}{100}:98=0,2\left(mol\right)\)
\(PTHH:\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
trc p/u : 0,3 0,2
p/u : 0,2 0,2 0,2 0,2
sau : 0,1 0 0,2 0,2
-> Fe dư
\(m_{ddFeSO_4}=0,3.56+49-0,4=65,4\left(g\right)\) ( ĐLBTKL )
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(C\%=\dfrac{30,4}{65,4}.100\%\approx46,48\%\)
PTHH :
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(a,m_{Fe}=0,3.56=16,8\left(g\right)\)
\(b,C_M=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(c,n_{H_2SO_4}=\dfrac{\dfrac{49.40}{100}}{98}=0,2\left(mol\right)\)
\(\rightarrow n_{FeSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(m_{ddFeSO_4}=49+\left(0,2.56\right)-0,2.2=59,8\left(g\right)\)( định luật bảo toàn khối lượng )
\(C\%=\dfrac{30,4}{59,8}.100\%\approx50,84\%\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Làm gộp các phần còn lại
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1mol\\n_{H_2SO_4}=n_{H_2}=0,3mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
\(n_{Al}=\dfrac{13,5}{27}=0,5mol\)
\(n_{H_2SO_4}=\dfrac{98}{98}=1mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,5 1 0 0
0,5 0,75 0,25 0,75
0 0,25 0,25 0,75
\(V_{H_2}=0,75\cdot22,4=16,8l\)
Chọn B
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
a, \(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
b, \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{9,8}{9,8\%}=100\left(g\right)\)
c, Ta có: m dd sau pư = 5,6 + 100 - 0,1.2 = 105,4 (g)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{0,1.152}{105,4}.100\%\approx14,42\%\)
\(a,n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ \text{Vì }\dfrac{n_{Fe}}{1}>\dfrac{n_{H_2SO_4}}{1}\text{ nên sau p/ứ }Fe\text{ dư}\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,25\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,25\cdot22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=n_{Fe}-n_{Fe\left(\text{phản ứng}\right)}=0,4-0,25=0,15\left(mol\right)\\ \Rightarrow m_{Fe\left(dư\right)}=0,15\cdot56=8,4\left(g\right)\)
\(a,n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ m_{H_2SO_4}=200.19,6\%=39,2\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
bđ 0,3 0,4
pư 0,3 0,3
spư 0 0,1 0,3 0,3
\(\rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{dd}=19,5+200-0,3.2=218,9\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnSO_4}=\dfrac{0,3.161}{218,9}.100\%=22,06\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,1.98}{218,9}.100\%=4,48\%\end{matrix}\right.\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a, PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{H_2}=n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2\left(đkc\right)}=0,2.24,79=4,958\left(l\right)\\ c,C_{MddH_2SO_4}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0,3->0,3-->0,3->0,3\)
\(mH_2SO_4=0,3.98=29,4\left(g\right)\)
\(\Rightarrow C\%_{ddH_2SO_4}=\dfrac{29,4.100}{200}=14,7\%\)
\(V_{FeSO_4}=\dfrac{n}{CM}=\dfrac{0,3}{2}=0,25\left(l\right)\)
\(VH_2=0,3.22,4=6,72\left(l\right)\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 0,3
\(C\%_{H_2SO_4}=\dfrac{0,3.98}{200}.100\%=14,7\%\\ V_{FeSO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\\ V_{H_2}=0,3.22,4=6,72\left(l\right)\)