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Gọi $n_{Fe} = a(mol) ; n_{Al} = b(mol)$
$\Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{H_2} = a + 1,5b = 8,96 : 22,4 = 0,4(2)$
Từ (1)(2) suy ra a = 0,1 ; b = 0,2
Vậy :
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,91\%$
$\%m_{Al} = 100\% -50,91\% = 49,09\%$
\(n_{Al}=a\left(mol\right)\)
\(n_{Fe}=b\left(mol\right)\)
\(m=27a+56b=19.3\left(g\right)\left(1\right)\)
\(n_{H^+}=0.2\cdot2+0.2\cdot2.25\cdot2=1.3\left(mol\right)\)
\(2Al+6H^+\rightarrow2Al^{3+}+3H_2\)
\(Fe+2H^+\rightarrow Fe^{2+}+H_2\)
\(n_{H^+}=3a+2b=1.3\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.3,b=0.2\)
\(\%Al=\dfrac{0.3\cdot27}{19.3}\cdot100\%=41.96\%\)
\(\%Fe=58.04\%\)
\(b.\)
\(n_{H_2}=\dfrac{1}{2}n_{H^+}=0.65\left(mol\right)\)
Bảo toàn khối lượng :
\(m_{Muối}=19.3+0.4\cdot36.5+0.45\cdot98-0.65\cdot2=76.7\left(g\right)\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
\(2A1+2NAOH+2H_2O-2NaA10_2+H_2O\)
\(AI_2O_3=2NaOH+2NaOHA10_2+H_2O\)
\(n_{AI}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}.0,6=0,4\left(mol\right)\)
\(m_{AI}=27.0,4=10,8\left(gam\right);mAI_2O_3=31,2-10,8=20,4\left(gam\right)\)
Biết làm mỗi câu A
\(n_{NaOH}=0,4.0,5=0,2\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{NaOH}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{15,2}.100\%\approx78,95\%\\\%m_{C_2H_5OH}\approx21,05\%\end{matrix}\right.\)
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2 so mol cua 2 hon hop suy he pt tinh mol cua hcl tinh m hcl sau do tinh mddhcl dung cong thuc v=m/d tinh duoc vdd can t
a) Đặt nAl=a(mol) ; nFe=b(mol) (a,b>0)
nHCl= (365.12%)/36,5=1,2(mol)
PTHH: 2Al + 6 HCl -> 2AlCl3 +3 H2
a________3a_________2a____1,5a(mol)
Fe + 2 HCl -> FeCl2 + H2
b_____2b____b____b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}27a+56b=22,2\\3a+2b=1,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)
b) => %mAl= [(0,2.27)/22,2].100=24,324%
=>%mFe= 75,676%
c) mFeCl2=127. 0,3=38,1(g)
mAlCl3= 133,5. 0,2= 26,7(g)
mddsau= 22,2+365 - 1,2.2=384,8(g)
=>C%ddFeCl2= (38,1/384,8).100=9,901%
C%ddAlCl3= (26,7/384,8).100=6,939%
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} = b(mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{HCl} = 2a + 3b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,91\%$
$\%m_{Al} = 100\%- 50,91\% = 49,09\%$