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1)
Fe + 2HCl --> FeCl2 + H2
Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
2)
- Xét TN1:
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15<------------------0,15
=> mFe = 0,15.56 = 8,4 (g)
\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{8,4}{14,8}.100\%=56,757\%\\\%m_{Cu}=100\%-56,757\%=43,243\%\end{matrix}\right.\)
3)
- Xét TN2:
\(n_{Cu}=\dfrac{29,6.43,243\%}{64}=0,2\left(mol\right)\)
PTHH: Cu + 2H2SO4 --> CuSO4 + SO2 + 2H2O
0,2-------------------------->0,2
=> V = 0,2.22,4 = 4,48 (l)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15<--------------------0,15
=> \(\%Fe=\dfrac{0,15.56}{14,8}.100\%=56,757\%\)
=> \(\%Cu=100\%-56,757\%=43,243\%\)
nH2 = 3,36/22,4 = 0,15 (mol)
PTHH: Fe + 2HCl -> FeCl2 + H2
nFe = 0,15 (mol)
mFe = 0,15 . 56 = 8,4 (g)
%mFe = 8,4/14,8 = 56,75%
%mCu = 100% - 56,75% = 43,25%
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)
X+ HCl -> XCl + 1/2 H2
nH2=0,25(mol)
-> nHCl(ban đầu)= (2.0,25) . 110%=0,55(mol)
VddHCl= 0,55/2=0,275(l)=275(ml)
=>mddHCl=275.1,2=330(g)
mddA=mX+ mddHCl -mH2= 14,7+330-0,25.2=344,2(g)
Fe + 2HCl -->. FeCl2 + H2
0,15-----0,3
Cu không pứ với HCl
nH2 =3,36\22,4= 0,15 mol
=> nFe = 0,15 mol
=>mFe = 0,15.56 = 8,4 g
=>mCu=10-8,4=1,6g
=>mHCl=0,3.98=29,4g
=>mddHCl=80,55g