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Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
3. CuO +H2SO4 -->CuSO4 +H2O
nCuO=64/80=0,8(mol)
theo PTHH :nCuO =nH2SO4=nCuSO4=0,8(mol)
=>mddH2SO4 20%=0,8.98.100/20=392(g)
mCuSO4=0,8.160=128(g)
mdd sau phản ứng =64 +392=456(g)
mH2O=456 -128=328(g)
giả sử có a g CuSO4.5H2O tách ra
trong 250g CuSO4 tách ra có 160g CuSO4 và 90g H2O tách ra
=> trong a g CuSO4.5H2O tách ra có : 160a/250 g CuSO4 và 90a/250 g H2O tách ra
=>mCuSO4(còn lại)=128 -160a/250 (g)
mH2O (còn lại)=328 -90a/250 (g)
=>\(\dfrac{128-\dfrac{160a}{250}}{328-\dfrac{90a}{250}}.100=25\)
=>a=83,63(g)
a, \(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,4 0,8 0,4 0,4
\(V_{H_2}=0,4.22,4=8,96\left(l\right)\)
b, \(m_{Zn}=0,4.65=26\left(g\right)\)
c, mdd sau pứ = 26 + 200 - 0,4.2 = 225,2 (g)
\(C_{M_{ddZnCl_2}}=\dfrac{0,4.136.100\%}{225,2}=24,16\%\)
a)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
_____0,1<---0,2<-------0,1<---0,1
=> mHCl = 0,2.36,5 = 7,3 (g)
=> \(m_{ddHCl}=\dfrac{7,3.100}{7,3}=100\left(g\right)\)
mdd sau pư = 0,1.24 + 100 - 0,1.2 = 102,2 (g)
\(C\%\left(MgCl_2\right)=\dfrac{0,1.95}{102,2}.100\%=9,2955\%\)
b)
CTHH: AaOb
PTHH: \(A_aO_b+2bHCl->aACl_{\dfrac{2b}{a}}+bH_2O\)
____________0,2------->\(\dfrac{0,1a}{b}\)
=> \(\dfrac{0,1a}{b}\left(M_A+35,5.\dfrac{2b}{a}\right)=13,5\)
=> \(M_A=\dfrac{64b}{a}=\dfrac{2b}{a}.32\)
Nếu \(\dfrac{2b}{a}=1\) => MA = 32 (L)
Nếu \(\dfrac{2b}{a}=2\) => MA = 64(Cu)
Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
Theo đề bài ta có : ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol){VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol)
nFe = 1,68/56 = 0,03 mol
a) Ta có PTHH :
2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1mol......0,05mol
=> CMH2SO4 = 0,05/0,05=1(M)
\(6\\ a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=n_{FeCl_2}=0,1mol\\ V_{H_2}=0,1.24,79=2,479l\\ b)n_{HCl}=0,1.2=0,2mol\\ m_{ddHCl}=\dfrac{0,2.36,5}{3,65}\cdot100=100g\\ c)C_{\%FeCl_2}=\dfrac{0,1.127}{100+5,6-0,1.2}\cdot100=12,05\%\)
\(7\\ a)n_{H_2}=\dfrac{7,437}{24,79}=0,3mol\\ CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ n_{CO_2}=n_{CaCO_3}=0,3mol\\ \%m_{CaCO_3}=\dfrac{0,3.100}{63,6}\cdot100=47,17\%\\ \%m_{CaO}=100-47,17=52,83\%\)
\(n_{CaO}=\dfrac{63,6-0,3.100}{56}=0,6mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ n_{HCl}=0,3.2+0,6.2=1,8mol\\ m_{ddHCl}=\dfrac{1,8.36,5}{20}\cdot100=328,5g\)