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\(n_{CO2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Pt : \(C_6H_{12}O_6\xrightarrow[30-35^oC]{Menrượu}2C_2H_5OH+2CO_2\)
0,5 0,5
a) \(m_{C2H5OH}=0,5.46=23\left(g\right)\)
b) Pt : \(C_2H_5OH+O_2\xrightarrow[]{Mengiấm}CH_3COOH+H_2O\)
0,5 0,5
\(m_{CH3COOH\left(lt\right)}=0,5.60=30\left(g\right)\)
⇒ \(m_{CH3COOH\left(tt\right)}=30.80\%=24\left(g\right)\)
Chúc bạn học tốt
\(C_6H_{12}O_6\underrightarrow{t^o}2C_2H_5OH+2CO_2\uparrow\)(xt : men rượu )
0,5 0,5
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(m_{C_2H_5OH}=0,5.46=23\left(g\right)\)
\(C_2H_5OH+O_2\underrightarrow{t^o}CH_3COOH+H_2O\) (men giấm )
0,5 0,5
\(m_{CH_3COOH}=0,5.60=30\left(g\right)\)
\(m_{CH_3COOHtt}=30.80\%=24\left(g\right)\)
a, \(n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Mg}=0,1.24=2,4\left(g\right)\)
\(V=V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH}=n_{CH_3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
\(\Rightarrow V_{ddC_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\)
\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ a,n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\Rightarrow n_{CO_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\Rightarrow V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,CH_3COOH+C_2H_5OH⇌\left(H^+,t^o\right)CH_3COOC_2H_5+H_2O\\ n_{CH_3COOH}=\dfrac{50}{200}.0,2=0,05\left(mol\right)\\ n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\ Vì:\dfrac{0,5}{1}>\dfrac{0,05}{1}\Rightarrow Rượu.dư\\ \Rightarrow n_{este\left(LT\right)}=n_{axit}=0,05\left(mol\right)\\ \Rightarrow n_{este\left(TT\right)}=80\%.0,05=0,04\left(mol\right)\\ m_{CH_3COOC_2H_5}=88.0,04=3,52\left(g\right)\)
a)
$C_2H_5OH + CH_3COOH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O$
b)
n CH3COOC2H5 = n C2H5OH = 9,2/46 = 0,2(mol)
=> m este = 0,2.88 = 17,6 gam
c)
n este = 8,8/88 = 0,1(mol)
=> n C2H5OH = n CH3COOH = 0,1/60% = 1/6 mol
=> m C2H5OH = 46 . 1/6 = 7,67(gam) ; m CH3COOH = 60 . 1/6 = 10(gam)
PTHH: \(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\) (1)
\(2CH_3COOH+2Na\rightarrow2CH_3COONa+H_2\) (2)
a) Ta có: \(n_{H_2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)
Đặt số mol của \(C_2H_5OH\) là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=\frac{1}{2}a\)
Đặt số mol của \(CH_3COOH\) là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=\frac{1}{2}b\)
Ta có hệ phương trình:
\(\left\{{}\begin{matrix}46a+60b=20,5\\\frac{1}{2}a+\frac{1}{2}b=0,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,25\\b=0,15\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_5OH}=0,25mol\\n_{CH_3COOH}=0,15mol\end{matrix}\right.\)
\(\Rightarrow m_{CH_3COOH}=60\cdot0,15=9\left(g\right)\)
\(\Rightarrow\%m_{CH_3COOH}=\frac{9}{20,5}\cdot100\approx43,9\%\)
\(\Rightarrow\%m_{C_2H_5OH}=56,1\%\)
b) PTHH: \(C_2H_5OH+CH_3COOH\underrightarrow{xt}CH_3COOC_2H_5+H_2O\)
Xét tỷ lệ: \(\frac{0,15}{1}< \frac{0,25}{1}\) \(\Rightarrow\) Axit phản ứng hết, Rượu còn dư
\(\Rightarrow n_{CH_3COOC_2H_5}=0,15mol\) \(\Rightarrow m_{este}=0,15\cdot88=13,2\left(g\right)\)
\(\Rightarrow m_{este}thực=13,2\cdot90\%=11,88\left(g\right)\)
\(m_{C_2H_5OH}=88.0,8=70,4\left(kg\right)\)
\(C_2H_5OH+O_2\rightarrow\left(t^o,men.giấm\right)CH_3COOH+H_2O\)
46g `->` 32g `->` 60g
70,4kg `->` ?kg `->` ?kg
\(m_{O_2}=\dfrac{70,4.32}{46}=48,97\left(g\right)\)
\(V_{O_2}=\dfrac{48,97}{32}.22,4.90\%=30,85\left(m^3\right)\)
\(m_{CH_3COOH}=\dfrac{70,4.60.90}{46.100}=82,64\left(kg\right)\)