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`n_[Zn]=13/65=0,2(mol)`
`Zn + 2HCl -> ZnCl_2 + H_2 \uparrow`
`0,2` `0,4` `0,2` `(mol)`
`a)V_[H_2]=0,2.22,4=4,48(l)`
`b)C%_[HCl]=[0,4.36,5]/150 .100~~9,73%`
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\
pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
0,3 0,3 0,3
\(C\%_{H_2SO_4}=\dfrac{0,3.98}{150}.100\%=19,6\%\)
\(pthh:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,3 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(a) n_{Zn} = \dfrac{19,5}{65} = 0,3(mol) ; n_{HCl} = 0,35.2 = 0,7(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ n_{HCl} = 0,7 > 2n_{Zn} = 0,6 \to HCl\ dư\\ n_{H_2} = n_{Zn} = 0,3(mol) \Rightarrow V_{H_2} = 0,3.22,4 = 6,72(lít)\\ b) m_{dd\ HCl} = 350.1,05 = 367,5(gam)\\ m_{dd\ sau\ pư} = 19,5 + 367,5 - 0,3.2 = 386,4(gam)\\ \Rightarrow C\%_{ZnCl_2} = \dfrac{0,3.136}{386,4}.100\% = 10,56\%\\ c) C\%_{HCl} = \dfrac{0,7.36,5}{367,5}.100\% = 6,95\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\\
C\%_{HCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)
\(n_{Zn}=\dfrac{65}{65}=1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
1 1 1
\(b,V_{H_2}=1.22,4=22,4\left(l\right)\)
\(c,m_{ZnCl_2}=1.136=136\left(g\right)\)
\(m_{ddZnCl_2}=65+\left(\dfrac{2.36,5:15}{100}\right)-2\approx549,67\left(g\right)\)
\(C\%_{ZnCl_2}=\dfrac{136}{549,67}.100\%\approx24,74\left(\%\right)\)
\(d,H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
trc p/u 1 0,1875
p/u : 0,1875 0,1875 0,1875
sau: 0,8125 0 0,1875
\(n_{CuO}=\dfrac{15}{80}=0,1875\left(mol\right)\)
\(m_{Cu}=0,1875.64=12\left(g\right)\)