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a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,2-->0,15
=> V = 0,15.22,4 = 3,36 (l)
b)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,3<----------------------------0,15
=> mKMnO4(lý thuyết) = 0,3.158 = 47,4 (g)
=> \(m_{KMnO_4\left(tt\right)}=\dfrac{47,4.110}{100}=52,14\left(g\right)\)
a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
Câu 1)
a) 2HgO\(-t^0\rightarrow2Hg+O_2\)
b)Theo gt: \(n_{HgO}=\frac{2,17}{96}\approx0,023\left(mol\right)\\ \)
theo PTHH : \(n_{O2}=\frac{1}{2}n_{HgO}=\frac{1}{2}\cdot0,023=0,0115\left(mol\right)\\ \Rightarrow m_{O2}=0,0115\cdot32=0,368\left(g\right)\)
c)theo gt:\(n_{HgO}=0,5\left(mol\right)\)
theo PTHH : \(n_{Hg}=n_{HgO}=0,5\left(mol\right)\\ \Rightarrow m_{Hg}=0,5\cdot80=40\left(g\right)\)
Câu 2)
a)PTHH : \(S+O_2-t^0\rightarrow SO_2\)
b)theo gt: \(n_{SO2}=\frac{2,24}{22,4}=0,1\left(mol\right)\)
theo PTHH \(n_S=n_{SO2}=0,1\left(mol\right)\\ \Rightarrow m_S=0,1\cdot32=3,2\left(g\right)\)
Ta có khối lượng S tham gia là 3,25 g , khối lượng S phản ứng là 3,2 g
Độ tinh khiết của mẫu lưu huỳnh là \(\frac{3,2}{3,25}\cdot100\%\approx98,4\%\)
c)the PTHH \(n_{O2}=n_{SO2}=0,1\left(mol\right)\Rightarrow m_{O2}=0,1\cdot32=3,2\left(g\right)\)
a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
4P+5O2-to>2P2O5
0,04----0,05----0,02
n P=0,04 mol
=>m P2O5=0,02.142=2,84g
=>VO2=0,05.22,4=1,12l
c)
2KMnO4-to>K2MnO4+MnO2+O2
0,1----------------------------------------0,05
H=10%
m KMnO4=0,1.158.110%=17,28g
\(n_P=\dfrac{1,24}{31}=0,04\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{T^O}2P_2O_5\)
0,04 0,05 0,02
=> \(\left\{{}\begin{matrix}m_{P_2O_5}=0,02.142=2,84\left(g\right)\\V_{O_2}=0,05.22,4=1,12\left(l\right)\end{matrix}\right.\)
\(pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
=> \(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(m_{KMnO_4\left(d\text{ùng}\right)}=15,8.110\%=17,38\left(g\right)\)
bài 1
a.4Al+3O2->2Al2O3
nAl=5,4\27=0,2(mol)
nO2=0,2⋅34=0,15(mol)
VO2=0,15*22,4=3,36(l)
c.2KMnO4-to>K2MnO4+MnO2+O2
nKMnO4=0,15*2=0,3(mol)
=>mKMnO4=0,3*158=47,4(g)
do dư 10%
=>mKMnO4=474 g
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