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\(PTHH:2KNO_3\overset{t^0}{\rightarrow}2KNO_2+O_2\)
\(a,n_{O_2}=\frac{11,2}{32}=0,35mol\)
\(\Rightarrow n_{KNO_3}=\frac{0,35}{80}.101=44,1875g\)
\(b,n_{KNO_3}=\frac{40,4}{101}=0,4mol\)
\(\Rightarrow m_{O_2}=0,4.32.85\%=10,88g\)
a) V O2 cần dùng= 20 . 100=2000 ml=2 (l)
--> n O2 =\(\frac{2}{22,4}\)=\(\frac{5}{56}\)(mol)
2KMnO4 --t*--> K2MnO4 + MnO2 + O2
\(\frac{5}{28}\) <------- \(\frac{5}{56}\)(mol)
m KMnO4 = \(\frac{5}{28}\). 158 . (100% + 10%)= 31,04 (g)
b) 2KClO3 ----t*,V2O5----> 2KCl + 3O2 (nhiệt độ, xúc tác)
\(\frac{5}{84}\) <------- \(\frac{5}{56}\)(mol)
m KClO3=\(\frac{5}{84}\).122,5= 7,29(g)
a) Thể tích oxi cần dùng là : (lít).
Số mol khí oxi là : = 0,099 (mol).
Phương trình phản ứng :
2KMnO4 K2MnO4 + MnO2 + O2
2mol 1mol
n mol 0,099 mol
=> n = = 0,198 (mol).
Khối lượng Kali pemaganat cần dùng là :
m = 0,198. (39 + 55 + 64) = 31,3 (g).
b) Phương trình hóa học.
KClO3 2KCl + 3O2
2.122,5 gam 3.22,4 lít
m gam 2,22 lít
Khối lượng kali clorat cần dùng là :
m = (gam).
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
Cảm ơn bạn @anayuiky đã nhắc lỗi sai. Mình sửa lại ý c):
PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo phương trình \(n_{KMnO_4}=n_{O_2}.2=0,25.2=0,5mol\)
\(\rightarrow m_{KMnO_4}=0,5.\left(39+55+16.4\right)=79g\)
a. \(n_{H_2}=\frac{V}{22,4}=\frac{11,2}{22,4}=0,5mol\)
\(n_{O_2}=\frac{V}{22,4}=\frac{10,08}{22,4}=0,45mol\)
PTHH: \(2H_2+O_2\rightarrow^{t^o}2H_2O\)
Ban đầu: 0,5 0,45 mol
Trong pứng: 0,5 0,25 0,5 mol
Sau pứng: 0 0,2 0,5 mol
\(\rightarrow M_{O_2\left(dư\right)}=n.M=0,2.32=6,4g\)
b. Theo phương trình \(n_{H_2O}=n_{H_2}=0,5mol\)
\(\rightarrow m_{H_2O}=n.M=0,5.18=9g\)
c. PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9 0,45 mol
\(\rightarrow n_{KMnO_4}=\frac{2}{1}n_{O_2}=\frac{0,45.2}{1}=0,9mol\)
\(\rightarrow m_{KMnO_4}=n.M=0,9.158=142,2g\)
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)
a) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,45}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25----->0,5
=> \(m_{O_2\left(dư\right)}=\left(0,45-0,25\right).32=6,4\left(g\right)\)
b) \(m_{H_2O}=0,5.18=9\left(g\right)\)
c)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
